首页|分离硫酸根解决高盐废水蒸发器结垢难题

分离硫酸根解决高盐废水蒸发器结垢难题

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针对多晶硅高盐废水蒸发系统换热器严重结垢的问题,对结垢物成分进行分析,结果表明结垢物主要成分为硫酸钙、少部分为硅酸钙.工艺分析排查显示,硫酸根主要来源于中水回用装置反渗透浓水,硅酸钙来源于酸性气体水洗产生的二氧化硅,主要原因为蒸发器加热系统管道内液体流速过慢及蒸发器未设置自动排污.基于此,本研究采取以下手段进行工艺优化和设备优化:反渗透出水增设除硬设备分离去除硫酸根,酸水中添加絮凝剂并加强机械过滤去除二氧化硅,来水中硫酸根降至100mg/L、二氧化硅降至50mg/L,此浓度不会造成加热器结垢;加热器列管内流速由1.5~1.7m/s提高至2.5m/s,蒸发器增设自动排污设备,从来水源头和设备改进优化两方面入手有效延长了加热器结垢周期,系统得以长周期平稳运行.
Study on the Treatment of Scale Formation of Poly silicon High-salt Waste water
Aiming at the problem of serious scaling of heat exchanger in polysilicon high-salt wastewater evaporation system,the composition of scaling was analyzed.The results showed that the main component of scaling was calcium sulfate and a small part was calcium silicate.Process analysis showed that sulfate mainly came from the reverse osmosis concentrated water of the water reuse device,and calcium silicate came from the silica produced by the acid gas washing.The main reason was that the liquid flow rate in the evaporator heating system pipe was too slow and the evaporator did not set up automatic sewage discharge.Based on this,the following means were adopted in this study for process optimization and equipment optimization:the reverse osmosis effluent was added with the addition of hard equipment to separate and remove sulfate,the acid water was added with flocculant and the mechanical filtration was strengthened to remove silica,and the sulfate and silica in the incoming water were reduced to 100mg/L and 50mg/L,which would not cause scaling of the heater;the flow rate in the heater tube was increased from 1.5-1.7m/s to 2.5m/s,and the evaporator was added with automatic sewage discharge equipment.Starting from the water source and the improvement and optimization of the equipment,the scaling cycle of the heater was effectively prolonged,and the system could run smoothly for a long period.

high-salt wastewaterscale formationsulfate radicalsilicon dioxide

张习松、慕道焱

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内蒙古通威高纯晶硅有限公司,内蒙古包头 014000

高盐废水 结垢物 硫酸根 二氧化硅

2024

化工设计
中国成达工程有限公司 中国石油和化工勘察设计协会

化工设计

影响因子:0.262
ISSN:1007-6247
年,卷(期):2024.34(1)
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