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DMTO碱洗废水的碱回收技术

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提出一种以特种膜组件为核心的碱回收技术,用以回收DMTO碱洗废水中的Na2CO3和NaOH.以内蒙古某甲醇制烯烃企业为例,通过中试装置探究并验证了碱回收效果.研究结果表明,气浮与陶瓷膜的预处理组合工艺对水中油状物去除率达到99.8%,有效保障碱回收膜组件的稳定运行.通过两级碱回收技术,每吨废水可回收获得19.12 kg的Na2CO3和1.77 kg的NaOH,碱回收率达到73.4%.本技术可实现废碱的循环利用,为企业节省大量药剂费用,创造良好的经济效益.
A New Technology for Recovering Alkali from DMTO Alkali-Washing Wastewater
A new recovery technology based on special membrane module was proposed to recover Na2CO3 and NaOH from DMTO alkali-washing wastewater in this paper.Recovery effect was studied and verified via pilot-scale devices by choosing a DMTO enterprise in Inner Mongolia as example.The results showed that the pre-treatment process,combined of air flotation and ceramic membrane,could remove 99.8%of oil in water,which effectively guarantee the stable operation of alkali-recovery membrane module.Recovery rate of alkali was calculated as 73.4%,and 19.12 kg Na2CO3 and 1.77 kg NaOH could be recovered from per ton of wastewater through the two-stage alkali-recovery technology.The recycling of waste alkali via this technology would create considerable benefits for enterprise by saving large amounts of pharmaceutical costs.

DMTO alkali-washing wastewaterspecial membrane moduletwo-stage alkali-recovery technologysodium carbonate

程会军、陈梦帆

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中煤鄂尔多斯能源化工有限公司,内蒙古鄂尔多斯 017317

上海凯鑫分离技术股份有限公司,上海 200136

DMTO碱洗废水 特种膜组件 两级碱回收 碳酸钠溶液

2024

化工设计通讯
湖南化工医药设计院

化工设计通讯

影响因子:0.126
ISSN:1003-6490
年,卷(期):2024.50(5)
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