首页|基于离子液晶的钙钛矿界面工程提升开路电压

基于离子液晶的钙钛矿界面工程提升开路电压

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钙钛矿器件衬底至关重要.自组装小分子层[2-(3,6-二甲氧基-9H-咔唑-9-基)乙基]膦酸修饰氧化镍后,表面与钙钛矿失配.通过离子液晶1-十二烷基-3-甲基咪唑四氟硼酸盐修饰埋底界面,改善界面接触,与碘化铅相互作用,提升晶体质量和极小化电压损失.钙钛矿太阳电池开路电压从1.10 eV提升到1.15 eV,光电转换效率从19.48%提升到20.81%.这为反型钙钛矿太阳电池的埋底界面工程提供了新的思路.
Perovskite Interface Engineering to Increase Open Circuit Voltage By Ionic Liquid Crystal
The substrate of perovskite solar cells(PSC)is crucial.After modifying nickel oxide(hole transport layer)with the self-assembled small-molecule,surface by[2-(3,6-dimethoxy-9H-carbazol-9-yl)ethyl]phosphonic acid mismatched with perovskite.By modifying the buried interface,ionic liquid crystal(ILC),1-dodecyl-3-methylimidazolium tetrafluoroborate,improves interface contact,interacts with lead iodide,enhance s crystal quality and minimizes voltage loss.The open circuit voltage of PSC increased from 1.10 eV to 1.15 eV,and the power conversion efficiency increased from 19.48%to 20.81%.This provides a new approach for the buried interface engineering of inverted PSC.

ionic liquid crystalburied interfacecrystal growthopen-circuit voltage

胡可馨、于华、陈靖禹

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西南石油大学 新能源与材料学院,四川成都 610500

反型钙钛矿太阳电池 离子液晶 埋底界面 晶体生长 开路电压

2024

化工设计通讯
湖南化工医药设计院

化工设计通讯

影响因子:0.126
ISSN:1003-6490
年,卷(期):2024.50(11)