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河口区高氯河水对化学需氧量测定的影响研究

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化学需氧量(CODcr)是衡量水质污染的一项重要指标,其测定的准确性受多种因素的影响.对于入海河口,氯离子对CODcr测定值的干扰明显.研究表明,河口区水中氯离子有时高达10 000 mg/L,这类河水用标准方法测定CODcr时,其值往往产生较大的正误差.通过对高氯河水CODcr测定时氯离子干扰与氧化剂浓度的关系研究发现,氧化剂浓度对氯离子干扰程度有较大的影响.根据研究结果,提出了用分段重铬酸钾法测定高氯河水CODcr的设想,并对此设想进行了验证.
A Study on the Influence of High Chlorine River Water in the Estuary Area on the Determination of Chemical Oxygen Demand
Chemical oxygen demand(CODcr)is an important indicator for measuring water pollution,and its accuracy is influenced by various factors.For estuaries,the interference of chloride ions on CODcr measurement values is significant.Research has shown that chloride ions in estuarine water can sometimes reach up to 10 000 mg/L,and the determination of CODcr in such river water using standard methods often results in significant positive errors.Through the study of the relationship between chloride ion interference and oxidant concentration in the determination of CODcr in high chloride river water,it was found that oxidant concentration has a significant impact on the degree of chloride ion interference.The idea of using segmented potassium dichromate method to determine CODcr in high chloride river water was proposed based on the research results,and this idea was verified.

estuary of the seachemical oxygen demandhigh chlorine river waterinfluence

林达、李婷、林晓杰

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福建省环境监测中心站,福建 福州 350003

入海河口 化学需氧量 高氯河水 影响

2024

化工设计通讯
湖南化工医药设计院

化工设计通讯

影响因子:0.126
ISSN:1003-6490
年,卷(期):2024.50(12)