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基于限制原则的环氧乙烷催化剂末期运行优化

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限制原则在工业生产中发挥着至关重要的作用,它强调在有限的资源条件下,通过合理地配置和优化,提高装置安全性,实现生产效益的最大化.在环氧乙烷催化剂末期运行优化中,需要充分考虑催化剂的活性、选择性等关键参数,优化影响催化剂性能的反应物浓度、调节剂加入量、二氧化碳浓度等限制因素,重点关注运行末期可能出现的床层热点、飞温、尾烧等安全风险.本文基于限制原则的本质安全化设计,对S-893银催化剂末期运行进行攻关,通过严格参数控制,优化运行指标,使催化剂末期运行指标优于预期,反应温度稳定,时空产率在240.7 kgEOE/(m3·h),选择性一直保持在87%以上.
Optimization of End Stage Operation of Ethylene Oxide Catalyst Based on Restriction Principle
The principle of limitation plays a crucial role in industrial production,emphasizing the improvement of equipment safety and the maximization of production efficiency through rational allocation and optimization under limited resource conditions.In the optimization of the final operation of ethylene oxide catalysts,it is necessary to fully consider key parameters such as catalyst activity and selectivity,optimize limiting factors such as reactant concentration,regulator dosage,and carbon dioxide concentration that affect catalyst performance,and focus on safety risks such as bed hotspots,flash temperatures,and tail burning that may occur during the final operation.this article is based on the principle of intrinsic safety design and focuses on the late stage operation of S-893 silver catalyst.Through strict parameter control and optimization of operating indicators,the catalyst's late stage operating indicators are better than expected,the reaction temperature is stable,the space-time yield is 240.7 kg EOE/(m3·h),and the selectivity has been maintained at over 87% .

silver catalystethylene oxidefinal operationselectivityactivity

张少雄

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中国石化扬子石油化工有限公司,江苏 南京 210048

银催化剂 环氧乙烷 末期运行 选择性 活性

2024

化工设计通讯
湖南化工医药设计院

化工设计通讯

影响因子:0.126
ISSN:1003-6490
年,卷(期):2024.50(12)