化工时刊2024,Vol.38Issue(1) :16-20.DOI:10.16597/j.cnki.issn.1002-154x.2024.01.004

复合氧化物负载杂多酸催化剂上乙酰丙酸加氢性能

Hydrogenation of Levulinic Acid over Composite Oxide Supporting Heteropolyacid Catalyst

邵振宇 王紫琪 姚明珠 肖国民 魏瑞平
化工时刊2024,Vol.38Issue(1) :16-20.DOI:10.16597/j.cnki.issn.1002-154x.2024.01.004

复合氧化物负载杂多酸催化剂上乙酰丙酸加氢性能

Hydrogenation of Levulinic Acid over Composite Oxide Supporting Heteropolyacid Catalyst

邵振宇 1王紫琪 1姚明珠 1肖国民 1魏瑞平1
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作者信息

  • 1. 东南大学化学化工学院,南京 211189
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摘要

采用浸渍法制备了铜锌铁复合氧化物负载硅钨酸催化剂,用XRD,BET以及SEM等手段表征了催化剂的物化性质,并考察了催化剂催化乙酰丙酸(LA)加氢的性能.结果表明,硅钨酸的加入可以明显提升催化剂在LA加氢反应中的活性.其中以CuZnFe-30SiW为催化剂,水为溶剂,在反应温度180 ℃,反应时间6 h,初始氢气压力4 MPa的条件下,LA的转化率超过95%,γ-戊内酯的收率达到85%以上.

Abstract

Cu-Zn-Fe composite oxide supporting silicotungstic acid catalyst was prepared by impregnation method,characterized with XRD,BET and SEM,and investigated in the hydrogenation performance of levulinic acid(LA).The results showed that the addition of silicotungstic acid can significantly improve the reaction performance of the catalyst.Using water as solvent,the CuZnFe-30SiW catalyst demonstrated more than 95%of LA conversion and more than 85%of γ-valerolactone yield under 180 ℃ of reaction temperature,6 hours of reaction time,4 MPa of initial hydrogen pressure conditions.

关键词

乙酰丙酸/γ-戊内酯/硅钨酸/复合氧化物/加氢

Key words

levulinic acid/γ-valerolactone/silicotungstic acid/compound oxide/hydrogenation

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出版年

2024
化工时刊
东南大学

化工时刊

影响因子:0.333
ISSN:1002-154X
参考文献量9
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