化工学报2024,Vol.75Issue(2) :715-726.DOI:10.11949/0438-1157.20231213

温度及其波动对橡胶密封硫化过程影响的仿真分析

Numerical analysis of the effect of temperature and its fluctuations on the vulcanization process of rubber seals

张兆想 蔡茂坤 任志英 贾晓红 郭飞
化工学报2024,Vol.75Issue(2) :715-726.DOI:10.11949/0438-1157.20231213

温度及其波动对橡胶密封硫化过程影响的仿真分析

Numerical analysis of the effect of temperature and its fluctuations on the vulcanization process of rubber seals

张兆想 1蔡茂坤 1任志英 1贾晓红 2郭飞2
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作者信息

  • 1. 福州大学机械工程及自动化学院,福建 福州 350108
  • 2. 清华大学高端装备界面科学与技术全国重点实验室,北京 100084
  • 折叠

摘要

硫化是橡胶密封成型过程的关键工艺,对橡胶密封产品性能有决定性影响.目前橡胶行业多采用经验式硫化成型方法,对橡胶密封硫化演变过程缺乏理解,难以理论指导橡胶密封实际生产过程.针对这一制约橡胶密封质量提升的薄弱环节,开展了橡胶密封硫化成型过程数值仿真研究.基于胶料的积分型反应动力学模型与变物性参数传热控制方程,建立了橡胶制品热-化学耦合的瞬态仿真模型,实现了橡胶制品成型过程时变温度场及硫化程度场的实时预测,并通过试验验证了模型及求解方法的正确性.进而,仿真分析了典型结构密封件的硫化过程,探讨了模具温度、胶料预热温度和温度波动行为对橡胶密封硫化成型过程的影响规律,最后为橡胶密封实际硫化生产提供了参考.

Abstract

As a key process in the rubber sealing molding,vulcanization has a significant impact on the performance of rubber sealing products.However,the rubber industry often adopts empirical vulcanization molding methods,lacking understanding of the evolution of vulcanization,making it difficult to theoretically guide the actual production process of rubber seals.In response to this weak link that restricts the improvement of rubber sealing quality,the paper conducted numerical simulation research on the vulcanization molding process of rubber seals.A transient simulation model for thermal-chemical coupling of rubber products was established based on an integral reaction kinetics model and a heat transfer control equation with variable physical parameters.Real time prediction of the time-varying temperature field and vulcanization degree field during the rubber product forming process was achieved,and the correctness of the model and solution method was verified through experiments.Furthermore,the vulcanization process of typical structural seals was simulated and analyzed,and the influence of mold temperature,rubber preheating temperature and temperature fluctuation behavior on the rubber seal vulcanization molding process was discussed.Finally,suggestions and references were provided for the actual vulcanization production of rubber seals.

关键词

橡胶密封/加工制造/反应动力学/温度波动/数值分析

Key words

rubber seals/fabrication/reaction kinetics/temperature fluctuations/numerical analysis

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基金项目

国家自然科学基金(52305186)

国家自然科学基金(U2330202)

福建省中青年教师教育科研项目(JAT220024)

福州大学引进人员科研启动基金(XRC-23064)

出版年

2024
化工学报
中国化工学会 化学工业出版社

化工学报

CSTPCDCSCD北大核心
影响因子:1.26
ISSN:0438-1157
参考文献量30
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