首页|基于LiCl-NH4Cl水溶液多级逆电渗析性能的实验研究

基于LiCl-NH4Cl水溶液多级逆电渗析性能的实验研究

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与单级逆电渗析相比,多级逆电渗析(multi-stage reverse electrodialysis,MSRED)在逆电渗析热机输出功率方面更具有优势,因其可将更多的溶液盐差能转换为电能.为进一步提高MSRED的输出功率,对比研究了先前开发的LiCl-NH4Cl水溶液(质量摩尔比为2∶8)与传统NaCl水溶液在作为MSRED工作溶液时装置的总净输出功率.结果表明,采用LiCl-NH4Cl水溶液的MSRED能够实现大电流输出,且与等质量摩尔浓度的NaCl水溶液相比,MSRED的总净输出功率最高提升28.6%.另外,无论相关工况参数如何变化,采用LiCl-NH4Cl水溶液的MSRED均能获得比等质量摩尔浓度的NaCl水溶液条件下更高的总净输出功率;同时系统所使用的电堆数量更少,从而可节省设备成本并减小装置体积.
Experimental study on the performance of multi-stage reverse electrodialysis based on LiCl-NH4Cl aqueous solution
Compared with single-stage reverse electrodialysis,multi-stage reverse electrodialysis(MSRED)has more advantages in the output power of reverse electrodialysis heat engine,because it can convert more salinity gradient energy into electricity.In order to further improve the output power of MSRED,the total net output power of the device when used as the MSRED working solution was compared between the previously developed LiCl-NH4Cl aqueous solution(mass molar ratio of 2:8)and the traditional NaCl aqueous solution.The parameters include current density,initial molality concentration of feed solution and the flow velocity of feed solution.The results show that MSRED with LiCl-NH4Cl aqueous solution can achieve higher current output,and the total net output power of MSRED can be increased by up to 28.6%compared with that of NaCl aqueous solution with the same mass molar concentration.In addition,no matter how the relevant operating parameters change,the MSRED using LiCl-NH4Cl aqueous solution can obtain higher total net output power than that of NaCl aqueous solution with the same mass molar concentration.At the same time,the number of stacks employed in the system is smaller,which can save equipment costs and reduce the volume of the device.

multi-stage reverse electrodialysissalinity gradient energysolutionheat enginemixturesion exchange

胡军勇、胡亚丽、谭学诣、黄佳欣、张乐炜、曾俊立、刘晓奕、陶源

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太原理工大学电气与动力工程学院,山西太原 030024

多级逆电渗析 盐差能 溶液 热机 混合物 离子交换

山西省基础研究计划青年科学研究项目中国博士后科学基金项目

2021030212230952021M702418

2024

化工学报
中国化工学会 化学工业出版社

化工学报

CSTPCD北大核心
影响因子:1.26
ISSN:0438-1157
年,卷(期):2024.75(7)