化工学报2024,Vol.75Issue(9) :3369-3378.DOI:10.11949/0438-1157.20240350

表面活性剂对含盐双流体细水雾灭火效能的影响

Effect of surfactants on fire extinguishing efficiency of salted double fluid fine water mist

裴蓓 郝治斌 徐天祥 钟子琪 李瑞 贾冲 段玉龙
化工学报2024,Vol.75Issue(9) :3369-3378.DOI:10.11949/0438-1157.20240350

表面活性剂对含盐双流体细水雾灭火效能的影响

Effect of surfactants on fire extinguishing efficiency of salted double fluid fine water mist

裴蓓 1郝治斌 2徐天祥 2钟子琪 2李瑞 2贾冲 2段玉龙3
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作者信息

  • 1. 河南理工大学煤炭安全生产与清洁高效利用省部共建协同创新中心,河南焦作 454003;河南理工大学安全科学与工程学院,河南焦作 454003
  • 2. 河南理工大学安全科学与工程学院,河南焦作 454003
  • 3. 重庆科技大学安全工程学院,重庆 401331
  • 折叠

摘要

为探究不同类型表面活性剂对含盐双流体细水雾灭火效能的影响,选用十二烷基苯磺酸钠(SDBS)、椰油酰胺丙基甜菜碱(CAB35)、烷基糖苷(APG0810),从灭火时间、冷却效果、CO浓度峰值三方面开展表面活性剂对含盐双流体细水雾灭火效能影响研究.结果显示:在空气环境下,3种表面活性剂可以有效缩短含盐类添加剂细水雾灭火时间,从而降低其灭火过程中的CO浓度峰值,但同时由于其液滴粒径减小,容易受到湍流影响,导致其冷却效果相比含单一盐类添加剂细水雾有所降低.在CO2环境下,由于CO2比定压热容较小,表面活性剂在对含单一盐类添加剂细水雾改性后分别存在灭火时间微幅缩短和灭火时间延长的实验现象,并且相比含单一盐类添加剂细水雾,其灭火过程中的CO浓度峰值有所增大,冷却效果也有所降低.研究结果将为防治醇基燃料火灾提供参考.

Abstract

In order to explore the effects of different types of surfactants on the fire extinguishing efficiency of two-fluid water mist containing salt additives,In this experiment,sodium dodecyl benzene sulfonate(SDBS),cocamidopropyl betaine(CAB35)and alkyl glucoside(APG0810)were selected to study the effects of surfactants on the fire extinguishing efficiency of salt-containing two-fluid water mist from three aspects:fire extinguishing time,cooling effect and CO concentration peak.The results show that in the air environment,the three surfactants can effectively shorten the fire extinguishing time of water mist containing salt additives,thereby reducing the peak CO concentration in the fire extinguishing process.Among them,4%APG0810 has the best fire extinguishing effect on the modified two-fluid water mist containing 5%K2CO3,and the fire extinguishing time is 29%shorter than that containing 5%K2CO3 two-fluid water mist.Compared with air/water mist,the fire extinguishing time is reduced by 55%,but at the same time,due to the decrease of the particle size of the surfactant,it is easy to be affected by turbulence,resulting in the cooling effect of the water mist containing salt additives.In the CO2 environment,due to the small specific heat capacity of CO2,the surfactants have the experimental phenomenon of slightly shortening the fire extinguishing time and extending the fire extinguishing time after modifying the fine water mist containing a single salt additive.And compared with salt-containing additive water mist,the peak CO concentration in the fire extinguishing process also increased,and the cooling effect also decreased.The research results will provide reference for prevention and control of alcohol-based fuel fires.

关键词

双流体细水雾/二氧化碳/表面活性剂/乙醇火/安全

Key words

double flow fine water mist/carbon dioxide/surfactants/ethanol fire/safety

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基金项目

河南省高校科技创新人才支持计划项目(22HASTIT027)

河南省高校基本科研业务费专项(NSFRF210344)

河南省科技攻关计划项目(222102320142)

出版年

2024
化工学报
中国化工学会 化学工业出版社

化工学报

CSTPCD北大核心
影响因子:1.26
ISSN:0438-1157
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