首页|常温条件下赤泥同时脱硫脱硝实验研究

常温条件下赤泥同时脱硫脱硝实验研究

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采用固定床反应器研究了赤泥在110℃条件下的同时脱硫脱硝反应性能,以及水蒸气浓度和硫硝比对其的影响.采用氮气吸附仪、pH计、电导率计、激光粒度分析仪和电感耦合等离子体质谱仪等分析手段测试了赤泥的物理性质和化学组成.实验结果表明,赤泥的脱硝效率是Ca(OH)2的2.4倍;反应气体中NO含量对SO2的脱除影响只有不到15%,而硫硝比接近5时,NO的脱除率接近100%;水蒸气的影响存在10%附近的最佳范围,浓度过高会影响前期NO的转化及脱除,但有利于后期的脱硫脱硝效果.赤泥中脱硫脱硝的有效组分包括碱性成分和金属氧化物.
Experimental study on simultaneous desulfurization and denitrification of red mud at low temperature
A fixed-bed reactor was used to study the simultaneous desulfurization and denitrification of red mud at 110℃,as well as the effects of water vapor concentration and SO2 to NO ratio.The physical properties and chemical composition of red mud were measured by BET(Brunauer Emmet Teller)surface area and porosity analyzer,pH meter,laser particle size analyzer(LDSA)and ICP(inductivity coupled plasma mass spectrometry).The experimental results showed that the denitrification efficiency of red mud was 2.4 times that of Ca(OH)2.The effect of NO content in the reaction gas on the removal of SO2 was less than 15%.When the SO2 to NO ratio approached 5,the removal efficiency of NO nearly approached 100%.The optimal range for the effect of water vapor was around 10%.When the water vapor concentration was too high,the conversion and removal of NO can be affected in the early stage,while the desulfurization and denitrification in the later stage were promoted.The effective components for desulfurization and denitrification in red mud mainly included alkaline components and metal oxides.

waste treatmentabsorptionfixed-bedsimultaneous desulfurization and denitrificationred mudgas-solid reaction

赵昂然、韩永强、王志鹏、李鹏飞、许亚伟、佟会玲

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清华大学能源与动力工程系,北京 100084

中冶建筑研究总院有限公司,北京 100088

废物处理 吸收 固定床 同时脱硫脱硝 赤泥 气固反应

2024

化工学报
中国化工学会 化学工业出版社

化工学报

CSTPCD北大核心
影响因子:1.26
ISSN:0438-1157
年,卷(期):2024.75(z1)