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不同制液工艺对锰矿锰浸出回收及钙镁铁迁移影响

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针对当前电解金属锰制液工艺锰浸出和回收率低的问题,以制液工艺为研究对象,开展现有工业生产制液工艺(T1)、阳极液浸洗(T2)、阳极液浸洗-水洗(T3)制液工艺模拟实验,研究不同制液工艺对锰矿中锰的浸出和回收以及钙镁铁迁移的影响.结果显示,锰浸出率T3(92.76%±0.40%)≈T2(92.14%±0.62%)>T1(89.59%±2.43%),锰回收率T3(91.18%±0.47%)>T2(87.02%±0.74%)>T1(73.97%±2.37%),表明在现有制液工艺基础上增加阳极液浸洗工序可以有效提高锰矿中锰的浸出率和回收率,增加水洗工序可以进一步提高浸出锰的回收率;在现有制液工艺基础上阳极液浸洗工序不会提高锰矿中钙、镁向液相的迁移比例,但会提高铁的迁移比例,增加水洗工序不会提高锰矿中钙、铁向液相的迁移比例,但会提高镁的迁移比例.
Effects of different liquid production processes on manganese leaching and recovery and migration of calcium,magnesium and iron in manganese ore
Aiming at the problem of low manganese leaching and recovery in the current electrolytic manganese metal liquid-making process,this paper takes the liquid-making process as the research object,carries out the simulation experiments of the existing industrial production liquid-making process(T1),anode liquid leaching(T2),anode liquid leaching-washing(T3)liquid-making process,and researches the influence of different liquid-making processes on the leaching and recovery of manganese in manganese ores,as well as on the migration of calcium,magnesium and iron.The results showed that the manganese leaching rate was T3(92.76%±0.40%)≈T2(92.14%±0.62%)>T1 were carried out to study the effects of different liquid preparation processes on the leaching rate and recovery rate of manganese and the migration of calcium,magnesium and iron in manganese(89.59%±2.43%),and the manganese recovery rate was T3(91.18%±0.47%)>T2(87.02%±0.74%)>T,(73.97%±2.37%),indicating that the leaching rate and recovery rate of manganese in manganese ore can be effectively improved by anodic leaching,and the recovery rate of manganese leaching can be effectively improved by washing process.On the basis of the existing liquid production process,the anodic leaching process will not increase the migration proportion of calcium and magnesium in manganese ore to the liquid phase,but will increase the migration proportion of iron,and the addition of the washing process will not increase the migration proportion of calcium and iron in manganese ore to the liquid phase,but will increase the migration proportion of magnesium.

anodic immersionanodic immersion-water washingmanganese leaching ratemanganese recovery ratemigration of calcium,magnesium and iron

赵博超、聂一凡、王雪婷、田向勤、田祎、潘涔轩

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中国环境科学研究院,国家环境保护生态工业重点实验室,北京 100012

生态环境部固体废物与化学品管理技术中心,北京 100029

阳极液浸洗 阳极液浸洗-水洗 锰浸出率 锰回收率 钙镁铁迁移

2024

化工学报
中国化工学会 化学工业出版社

化工学报

CSTPCD北大核心
影响因子:1.26
ISSN:0438-1157
年,卷(期):2024.75(z1)