首页|丙烯酰氧基/全氟聚醚基共改性氟硅树脂的制备及性能研究

丙烯酰氧基/全氟聚醚基共改性氟硅树脂的制备及性能研究

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以全氟聚醚硅烷、氟烃基硅烷、氨基硅烷、y-甲基丙烯酰氧基丙基三甲氧基硅烷和苯基硅烷等为原料,经水解共缩聚,制备得到y-甲基丙烯酰氧基丙基与全氟聚醚共改性的光固化氟硅树脂(PFSi)。通过红外光谱(FT-IR)、扫描电镜(SEM)等表征方法对其进行测试,并对涂层整体性能进行研究。结果表明:氟组分质量含量为20%时所制树脂所构筑的光固化涂层UVPFSi表面疏水效果较好,水接触角可达到118°,透光率达到90。83%,涂层经5%硫酸浸泡及耐盐雾测试后表面完好,整体表现出优异的耐化学腐蚀性。
Preparation and properties of acryloxy/perfluoropolyether group co-modified fluorosilicone resin
The photocurable fluorosilicone resin(FPSi)co-modified by y-methylacryloxy-propyl trimethoxy-silane and phenylsilane was prepared from perfluoropolylether,fluoroalkyl silane,amino-silane,y-methylacryloxy-propyl trimethoxy-silane and phenylsilane by hydrolysis and co-condensation.The coating was characterized and tested by FT-IR and SEM,and the overall properties of the coating were studied.The results showed that,when the fluorine content was 20wt%,the surface hydrophobic effect of the photocurable coating UVFPSi was good,with a water contact angle of 118°,and a light transmittance of 90.83%.The coating surface was intact after 5wt%sulfuric acid immersion and salt spray resistance test,demonstrating excellent chemical resistance.

fluorosilicone resinphotocurable coatingperfluoropolyether

吴燕燕、安秋凤、焦岚姣、卢攀

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陕西科技大学陕西省轻化工助剂重点实验室,西安 710021

氟硅树脂 光固化涂层 全氟聚醚

2025

化工新型材料
中国化工信息中心

化工新型材料

北大核心
影响因子:0.357
ISSN:1006-3536
年,卷(期):2025.53(1)