化工新型材料2025,Vol.53Issue(1) :115-119,124.DOI:10.19817/j.cnki.issn1006-3536.2025.01.044

纤维素纳米纤维和LATP修饰的PEO固体电解质的制备及其性能研究

Preparation and performance study of cellulose nanofibers and LATP-modified PEO solid electrolyte

嵇晨豪 张汉泽 王欣欣 杨雅晴 黄锋林
化工新型材料2025,Vol.53Issue(1) :115-119,124.DOI:10.19817/j.cnki.issn1006-3536.2025.01.044

纤维素纳米纤维和LATP修饰的PEO固体电解质的制备及其性能研究

Preparation and performance study of cellulose nanofibers and LATP-modified PEO solid electrolyte

嵇晨豪 1张汉泽 1王欣欣 1杨雅晴 1黄锋林1
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作者信息

  • 1. 江南大学教育部生态纺织品重点实验室,无锡 214122
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摘要

采用静电纺丝制备了醋酸纤维素纳米纤维膜,并进行去乙酰化处理和引入Li1.4Al0.4Ti1.6(PO4)3无机颗粒对聚氧化乙烯(PEO)电解质进行改性,可提高离子电导率,锂离子迁移数以及锂硫电池的循环稳定性.结果表明:经纤维素纳米纤维和LATP改性的PEO固体电解质在60℃下离子电导率达3.43×10-4S/cm,锂离子迁移数达0.44,高于PEO固体电解质.改性PEO固体电解质在60℃,0.1C下初始放电比容量为844.13mAh/g,且达到了 50圈循环.

Abstract

Cellulose acetate nanofiber membranes were prepared by electrospinning,followed by deacetylation treatment,and Li1.4Al0.4Ti1.6(PO4)3 inorganic particles were introduced to modify the polyethylene oxide(PEO)electrolyte,which could improve ionic conductivity,lithium-ion migration number,and cycling stability of lithium-sulfur batteries.The results showed that the ionic conductivity of the cellulose nanofibers and LATP-modified PEO solid electrolyte reached 3.43×10-4S/cm at 60℃,and the lithium-ion migration number reached 0.44,which were higher than those of the unmodified PEO solid electrolyte.The modified PEO solid electrolyte exhibited an initial discharge-specific capacity of 844.13mAh/g at 60℃ and 0.1C,and achieved 50 cycles.

关键词

静电纺丝/PEO固体电解质/再生纤维素纳米纤维/锂硫电池

Key words

electrospinning/PEO solid electrolyte/regenerated cellulose nanofibers/lithium-sulfur battery

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出版年

2025
化工新型材料
中国化工信息中心

化工新型材料

CSCD北大核心
影响因子:0.357
ISSN:1006-3536
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