化工新型材料2025,Vol.53Issue(1) :152-157.DOI:10.19817/j.cnki.issn1006-3536.2025.01.028

PF基共固化HXNBR阻尼复合材料制备及界面表征

Preparation and interface characterization of PF-based co-curing HXNBR damping composite

张宗顺 梁森 石豪启 黄效建 吴召琦
化工新型材料2025,Vol.53Issue(1) :152-157.DOI:10.19817/j.cnki.issn1006-3536.2025.01.028

PF基共固化HXNBR阻尼复合材料制备及界面表征

Preparation and interface characterization of PF-based co-curing HXNBR damping composite

张宗顺 1梁森 1石豪启 1黄效建 1吴召琦1
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作者信息

  • 1. 青岛理工大学机械与汽车工程学院,青岛 266520
  • 折叠

摘要

提出了一种抗老化、耐高温和力学性能优异的酚醛树脂基(PF)共固化阻尼复合材料制备工艺和界面性能表征方法.根据高分子合成理论和正交试验研制了氢化羧基丁腈橡胶(HXNBR)在150℃与酚醛树脂基体共固化的材料组分,解决了 HXNBR与酚醛树脂不同步共固化的问题,开发了可与酚醛树脂共固化的粘弹性材料薄膜的制备工艺,研究了酚醛树脂基共固化复合材料的层间结合性能随HXNBR的厚度变化规律,并通过X射线光电子能谱(XPS)和傅里叶红外光谱(FT-IR)证明了界面处化学反应的发生.

Abstract

In this paper,the preparation process and interface performance characterization method of phenolic resin-based(PF)co-curing damping film composites with excellent aging resistance,high-temperature resistance and superior mechanical properties were proposed.Based on polymer synthesis theory and orthogonal experiments,the material components of hydrogenated carboxyl nitrile butadiene rubber(HXNBR)co-cured with phenolic resin matrix at 150℃ where developed,which addressed the problem of asynchronous co-curing between HXNBR and phenolic resin.The preparation process of viscoelastic material films capable of co-curing with phenolic resin was developed,and the variation rule of the interlayer bonding performance of phenolic resin-based co-curing composite materials with the HXNBR thickness was systematically studied.The occurrence of chemical reactions at the interface was confirmed by XPS and FT-IR.

关键词

共固化阻尼复合材料/正交试验/界面结合机理

Key words

co-curing damping composite/orthogonal experiments/interfacial bonding mechanism

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出版年

2025
化工新型材料
中国化工信息中心

化工新型材料

北大核心
影响因子:0.357
ISSN:1006-3536
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