化工新型材料2025,Vol.53Issue(1) :243-249.DOI:10.19817/j.cnki.issn1006-3536.2025.01.048

乙丙胶粉基聚丙烯热塑性弹性体的绿色制备及其高值化性能分析

Green preparation and high-value performance analysis of ethylene propylene rubber powder-based polypropylene thermoplastic elastomers

王艳秋 张明 柳峰 李杰 卢猛 李晓娟
化工新型材料2025,Vol.53Issue(1) :243-249.DOI:10.19817/j.cnki.issn1006-3536.2025.01.048

乙丙胶粉基聚丙烯热塑性弹性体的绿色制备及其高值化性能分析

Green preparation and high-value performance analysis of ethylene propylene rubber powder-based polypropylene thermoplastic elastomers

王艳秋 1张明 2柳峰 1李杰 1卢猛 3李晓娟1
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作者信息

  • 1. 徐州工业职业技术学院材料工程学院,徐州 221140
  • 2. 扬州大学化学化工学院,扬州 225002
  • 3. 江苏江昕科技股份有限公司,徐州 221300
  • 折叠

摘要

为了响应国家"双碳"战略,绿色制备了高强伸耐老化的乙丙胶粉基聚丙烯热塑性弹性体,优化了乙丙胶粉与聚丙烯的橡塑比,确定了相容剂的品种、用量,优化了乙丙胶粉与聚丙烯的化学接枝工艺.结果表明:环保相容剂2,4-二叔丁基过氧化异丙苯(BIBP)与硫磺S8并用,乙丙胶粉基聚丙烯热塑性弹性体的力学和耐老化性能优异,拉伸强度达20MPa,扯断伸长率达800%以上,可用于耐老化汽车配件、码头缓冲器、各种胶管胶板等产品的负碳制备.

Abstract

In order to respond to the national"double carbon"strategy,this paper greenly prepared an ethylene propylene rubber powder-based polypropylene thermoplastic elastomer with high strength and aging resistance,optimized the ratio of ethylene propylene rubber powder and polypropylene,determined the variety and dosage of compatibilizers,and optimized the chemical grafting process between ethylene propylene rubber powder and polypropylene.The experimental results showed that using environmentally friendly compatible agent 2,4-di-tert-butylperoxyisopropylbenzene(BIBP)together with sulfur S8 could make the rubber powder-based polypropylene thermoplastic elastomer have excellent mechanical and aging resistance.The tensile strength reached 20MPa,and the elongation at break was more than 800%.This material could be used in the preparation of negative carbon for aging resistant auto parts,pier buffers,various rubber hoses and plates as well as other products.

关键词

乙丙胶粉/聚丙烯/相容剂/生胶/胶粉基热塑性弹性体/高值化性能

Key words

ethylene-propylene rubber powder/polypropylene/compatibilizer/raw rubber/rubber powder-based thermoplastic elastomer/high-value performance

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出版年

2025
化工新型材料
中国化工信息中心

化工新型材料

CSCD北大核心
影响因子:0.357
ISSN:1006-3536
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