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无机-有机复配材料对Cd污染土壤的修复效应

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通过大田试验,研究了无机材料(海泡石、蒙脱土和骨粉)-有机物料(菌渣、鸡粪、牛粪和蚯蚓粪)复配材料对Cd污染土壤的钝化修复效应及其对土壤酶活性的影响。结果表明,有机-无机材料复配处理显著提高了土壤pH值,最大增加0。96个pH单位。不同处理下土壤中TCLP(Toxicity characteristic leaching procedure)提取态Cd含量均有所降低,海泡石+有机物料、蒙脱土+有机物料和骨粉+有机物料处理下分别较对照减少了12。5%-24。9%、10。4%-19。4%和12。0%-21。7%。与对照相比,不同复配处理下,玉米籽粒Cd含量降低22。8%-79。0%(骨粉+蚯蚓处理除外),低于国家食品卫生标准(0。1 mg·kg-1)。不同复配材料对土壤过氧化氢酶和脲酶活性促进效果整体上表现为骨粉+有机物料>蒙脱土+有机物料>海泡石+有机物料,较对照最大增幅分别达到74。4%、42。7%和10。5%。
Effect of inorganic-organic compound mixtures on the immobilization remediation of Cd contaminated soil
Field experiments were conducted to investigate the effects of inorganic materials (such as sepiolite,montmorilloniod and bone meal) and organic materials (e.g.fungi residue,chicken manure,cow dung and earthworm feces) on the immobilization remediation of Cd contaminated soils and soil enzyme activities.The results showed that organic-inorganic compound materials increased soil pH significantly,with a maximum increase of 0.96 pH units.The concentration of toxicity characteristic leaching procedure (TCLP)-Cd was reduced under the treatments of sepiolite + organic materials,montmorilloniod + organic materials and bone meal + organic materials,resulting in 12.5%-24.9%,10.4%-19.4% and 12.0%-21.7% reduction,respectively,when compared with the control groups.In comparison to the cented soils,the content of Cd in maize was reduced by 22.8%-79.0% (expect for the treatments of bone meal + earthworm feces),which was below the maximum permissible concentration of Cd set by the National Standard Agency of China (0.1 mg·kg-1).The decreasing order of catalase and urease activities was bone meal + organic materals > montmorilloniod + organic materials > sepiolite + organic materials,with a maximum increase of 74.4%,42.7% and 10.5%,respectively,in comparison to CK.

Cdimmobilization remediationinorganic materialsorganic materialssoil enzyme

纪艺凝、王农、徐应明、王润珑、孙约兵

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东北农业大学资源与环境学院,哈尔滨,150030

农业部环境保护科研监测所,农业部产地环境污染防控重点实验室,天津,300191

农业部环境保护科研监测所,天津市农业环境与农产品安全重点实验室,天津,300191

钝化修复 无机材料 有机物料 土壤酶

公益性行业(农业)科研专项天津市自然科学基金重点项目公益性行业基本科研业务费资助

20120304517JCZDJC34200

2017

环境化学
中国科学院生态环境研究中心

环境化学

CSTPCDCSCD北大核心
影响因子:1.049
ISSN:0254-6108
年,卷(期):2017.36(11)
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