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中低温NH3-SCR催化剂抗中毒与再生研究进展

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中低温氨选择性催化还原(NH3-SCR)氮氧化物(NOx)催化剂广泛应用于钢铁、焦化、陶瓷、玻璃、水泥、垃圾焚烧、燃气锅炉等非电行业。不同工况下,硫、酸、碱金属、飞灰等会导致SCR催化剂中毒。因此,如何制备抗中毒性能好的脱硝催化剂,并且有效再生失活SCR催化剂一直是研究热点。本综述针对不同中低温SCR的工况,对比总结脱硝催化剂的应用、抗中毒机制与再生方法,最后对中低温SCR脱硝催化技术进行展望。
Research progress on anti-poisoning and regeneration of catalysts at medium-low temperature NH3-SCR
The selective catalytic reduction(SCR)technology of NOx with NH3 at medium-low temperature are widely used in steel,coking,ceramics,glass,cement,waste incineration,gas boilers and other non-electric industries.Different working conditions,e.g.,sulfur,acid,alkali metals,fly ash,etc.lead to the poisoning of SCR catalysts.Therefore,SCR catalysts with the excellent anti-poisoning ability and regeneration performance are big challenges and attract more attention.This review compares and summarizes the antipoisoning mechanisms and regeneration methods under various industrial SCR conditions of medium-low temperature.Finally,the prospect of SCR technology at medium-low temperature is discussed.

medium-low temperature NH3-SCRdeNOxcatalystantipoisoning mechanismsregeneration

冯斌、邹伟欣、赵勇刚、董林

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南京大学环境学院,污染控制与资源化研究国家重点实验室,江苏省机动车尾气污染控制重点实验室,南京,210023

江苏诺环新材料科技有限公司,镇江,212415

中低温氨选择性催化还原 脱硝 催化剂 抗中毒 再生

国家自然科学基金

21972062

2024

环境化学
中国科学院生态环境研究中心

环境化学

CSTPCD北大核心
影响因子:1.049
ISSN:0254-6108
年,卷(期):2024.43(1)
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