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成都市餐饮源VOCs排放特征

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为研究成都市餐饮源VOCs排放特征,建立成都市餐饮源114种VOCs成分谱,本研究选择11个监测对象进行VOCs组分分析,并探索餐饮源VOCs全组分特征。结果表明,餐饮源VOCs中烷烃占比为23。12%—30。29%,烯烃占比为8。61%—25。78%,芳香烃占比为0。16%—5。86%,卤代烃占比为0。86%—13。82%,OVOCs 占比为 28。02%—63。77%,其他占比为 2。02%—8。26%。OVOCs、烷烃和烯烃3类占比最高,3类污染物累计质量浓度百分比在75%以上,是餐饮源重要的污染物类型。餐饮源排名前10的VOCs分别是丙烯醛(11。12%)、乙烷(9。87%)、乙醛(9。51%)、丙酮(9。34%)、乙烯(7。86%)、正戊烷(5。74%)、乙炔(5。01%)、丁二烯(4。64%)、顺式-1,3-二氯-1-丙烯(3。40%)和乙酸乙酯(3。04%),是餐饮源的特征污染物。餐饮源全组分分析得到OVOCs的代表性物质为反式茴香脑和芳樟醇等,烯烃代表性物质为长叶烯和柠檬烯等,烷烃代表性物质为正十五烷和正庚烷等,为完善餐饮源成分谱物种、探寻餐饮源特征污染物的研究提供参考。采用FAC法计算餐饮源VOCs二次有机气溶胶生成潜势。餐饮源SOA生成潜势为1220。7 μg·m 3,芳香烃SOA生成潜势贡献率为93。1%,烷烃SOA生成潜势贡献率为6。9%。
Emission characteristics of VOCs from catering sources in Chengdu
In order to study the emission characteristics of VOCs from catering sources and establish source profiles of 114 VOC species in Chengdu,we selected 11 different catering objects to sample and analysis VOC components and achieved to explore the feature of VOC emission from catering.The results from this work showed that the proportions of alkanes,olefins,aromatic hydrocarbons,halogenated hydrocarbons,OVOCs and others in VOC species from catering sources were 23.12%—30.29%,8.61%—25.78%,0.16%—5.86%,0.86%—13.82%,28.02%-63.77%and 2.02%—8.26%,respectively.OVOCs,alkanes and alkenes were the dominated categories and accounted for more than 75%of totally VOC emissions.The top 10 VOC species from catering sources were acrolein(11.12%),ethane(9.87%),acetaldehyde(9.51%),acetone(9.34%),ethylene(7.86%),n-pentane(5.74%),acetylene(5.01%),butadiene(4.64%),cis-1,3-dichloro-l-propene(3.40%),and ethyl acetate(3.04%).They were the typical organic compounds from catering sources.The full-component characteristics of VOCs from catering sources showed that the representative substances of OVOCs,olefins and alkanes were trans-anisole and linalool,long-leaf alkene and limonene,n-pentadecane and n-heptane,respectively.These results provided important information and references for characteristic investigation of catering sources.The FAC method was applied to estimate the potential amount of secondary organic aerosol(SOA)depending on VOC data from catering sources,the total SOA formation potential value was 1220.7 μg·m-3.Furthermore,aromatic hydrocarbons contributed 93.1%to this value and alkanes accounted for only 6.9%.

catering sourcessource profilevolatile organic compounds(VOCs)Chengdu City

胡秋萍、费怡、陈耀、周子航、张雷、杨亮、王斌、陈茁

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四川大学建筑与环境学院,成都,610065

成都市环境保护科学研究院,成都,610072

四川佳士特环境检测有限公司,成都,611700

成都市污染源监测中心成华区监测站,成都,610056

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餐饮源 成分谱 挥发性有机物(VOCs) 成都市

2024

环境化学
中国科学院生态环境研究中心

环境化学

CSTPCD北大核心
影响因子:1.049
ISSN:0254-6108
年,卷(期):2024.43(2)
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