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盐度波动对水体中污染物在水沙界面迁移的影响

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由于长江口河口在径流和潮流双重作用下,时常有盐水入侵现象的发生,且有长期存在的枯季"咸潮上溯北支倒灌进入南支"现象,因此盐度因子是影响水源地水质的重要因子之一。为保障用水安全以及精准预测水源地水质变化,本研究开展盐度波动对氨氮和总磷在水沙界面运移影响研究。结果表明,对于氨氮而言,水流扰动强度和盐度两者的影响效果可以同时提升其在泥沙颗粒相的吸附量,其中盐度的影响效果优于水流扰动强度;当盐度过高时,水沙分配系数随扰动强度增长呈抑制的趋势更明显。对于总磷而言,水流扰动强度和盐度两者的影响效果难以同时体现并解析,即当盐度为主要影响因素时,水流扰动强度对吸附量的影响基本可以忽略,反之亦然。
Impact of salinity fluctuation on partitioning behavior of pollutants at water-sediment interface
Due to the dual actions of runoff and tidal currents,seawater intrusion often occurs in the estuary of the Yangtze River,and there is a long-term phenomenon of"saltwater flows upstream from the North Branch to the South Branch"particularly in the dry season.Therefore,salinity is an important factor affecting the water quality of water source area.In order to ensure the safety of source water and accurately predict the alteration in its water quality,the influence of salinity and waterflow disturbance on water-sediment partitioning behavior of ammonia nitrogen(NH3-N)and total phosphorus(TP)was herein studied.Our results indicate that,for NH3-N,both turbulence intensity and salinity can increase the sorption on sediment,and the impact of salinity outweighed that of flow turbulence;when the salinity is too high,the water-sediment distribution coefficient shows an obviously restraining trend with the increase of disturbance intensity.For TP,the individual effects of both factors could not be clearly identified and delineated simultaneously.When salinity is the major factor,the effect of flow disturbance intensity on sorption of analytes on sediments can be ignored,and vice versa.

salinity fluctuationYangtze Estuarywater-sediment partitioningammonia nitrogentotal phosphorus

李保、唐诗月、曾一川

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长江水利委员会长江口水文水资源勘测局,上海,200136

河海大学环境学院,南京,210098

盐度波动 长江口 水沙界面迁移 氨氮 总磷

上海市水务局科研项目

沪水科2019-09

2024

环境化学
中国科学院生态环境研究中心

环境化学

CSTPCD北大核心
影响因子:1.049
ISSN:0254-6108
年,卷(期):2024.43(3)
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