首页|金昌市PM2.5的化学组分特征及来源分析

金昌市PM2.5的化学组分特征及来源分析

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为研究金昌市PM2。5及其化学组分(有机碳、元素碳和水溶性离子)的特征,于2020年5月—2021年3月对金昌市大气PM2。5进行手工采样,并运用PMF模型和HYSPLIT模型解析污染来源。研究结果表明,观测期间金昌市PM2。5年平均质量浓度为(62。2±10。4)μg·m-3,各季节平均质量浓度由高到低依次为春季、冬季、秋季、夏季。化学质量闭合研究表明:碳质组分(OM+EC)是金昌PM2。5的主要组成部分。PM2。5中的OC与EC的年平均质量浓度分别为(13。4±5。6)μg·m-3、(2。9±1。5)μg·m-3,TC占PM2。5质量浓度的16。3%,并且四季OC/EC的平均值均大于2,表明采样期间各个季节均存在二次污染。夏季OC与EC之间的相关系数最低,说明夏季污染物来源较其他季节更为复杂。金昌市PM2。5中总水溶性离子的年平均质量浓度为(25。0±11。6)μgm-3,占PM2。5质量浓度的40。2%,其中,SO42-、Ca2+、NO3-和Cl-是金昌市主要的4种离子,分别占总离子的22。5%、17。1%、16。8%、12。1%。对水溶性离子做离子平衡分析表明:夏季、秋季和冬季阴阳离子的相关性较好,没有重要的离子缺失,春季较差,有重要阴离子缺失。PMF模型表明金昌市PM2。5的主要污染源为燃烧源(生物质+燃煤)(30。5%)、土壤尘(24。6%)、二次无机气溶胶(26。0%)和机动车尾气(18。9%),HYSPLIT模型表明金昌市春季PM2。5浓度受外来污染源输入影响较大,夏季、秋季和冬季应主要考虑本地排放的贡献。
Chemical component characteristics and source analysis of PM2.5 in Jinchang City
In order to study the characteristics of PM2.5 and its chemical components(organic carbon,elemental carbon and water-soluble ions)in Jinchang City,manual sampling of atmospheric PM2.5 in Jinchang City was conducted from May 2020 to March 2021,and the PMF model and HYSPLIT model were used to analyze the sources of pollution.The results showed that the annual average mass concentration of PM2.5 was(62.2±10.4)μg·m-3 in Jinchang during the observation period,and the average mass concentration of PM2.5 was in spring,winter,autumn and summer from high to low.The chemical mass closure study shows that the carbon component(OM+EC)is the main component of PM2.5 in Jinchang.The average annual mass concentrations of OC and EC in PM2.5 were(13.4±5.6)μg·m-3 and(2.9±1.5)μg·m-3,respectively.TC accounted for 16.3%of PM2.5 mass concentration,and the average values of OC/EC in four seasons were greater than 2,indicating that secondary pollution existed in each season during the sampling period.The correlation coefficient between OC and EC in summer was the lowest,indicating that the pollutant sources in summer were more complex than in other seasons.The average annual mass concentration of total water-soluble ions in PM2.5 in Jinchang City is(25.0±11.6)μg·m-3,accounting for 40.2%of PM2.5 mass concentration,in which SO42-、Ca2+、NO3-and Cl-are the four main ions.They accounted for 22.5%,17.1%,16.8%and 12.1%of total ions respectively.The ion balance analysis of water-soluble ions showed that the correlation of canion in summer,autumn and winter was good,and there was no important ion deletion,while in spring it was poor,and there was important anion deletion.The PMF model showed that the main pollution sources of PM2.5 in Jinchang were combustion sources(biomass+coal)(34.4%),soil dust(25.2%),secondary inorganic aerosol(22.6%)and motor vehicle exhaust(18.0%).The HYSPLIT model showed that the PM2.5 concentration in Jinchang in spring was greatly affected by the input of external pollution sources.Summer,autumn and winter should mainly consider the contribution of local emissions.

PM2.5chemical compositionsource analysisJinchang City

喻恒、李忠勤、周茜、张昕、蒋慧敏、王芳龙、罗雨甜

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西北师范大学地理与环境科学学院,兰州,730070

中国科学院西北生态环境资源研究院冰冻圈科学国家重点实验室,兰州,730000

石河子大学理学院,石河子,832000

兰州大学资源环境学院,兰州,730000

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PM2.5 化学组分 来源分析 金昌市

青藏高原综合科学考察研究项目(第二次)中国科学院战略性先导科技专项(A类)冰冻圈科学国家重点实验室自主课题新疆综合科学考察研究项目(第三次)国家自然科学基金

2019QZKK0201XDA20060201SKLCS-ZZ-20222021xjkkl40141471058

2024

环境化学
中国科学院生态环境研究中心

环境化学

CSTPCD北大核心
影响因子:1.049
ISSN:0254-6108
年,卷(期):2024.43(4)
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