首页|典型电镀场地重金属污染及迁移特征

典型电镀场地重金属污染及迁移特征

扫码查看
重金属污染是电镀场地普遍现象,研究其土壤地下水中重金属污染特征和迁移影响因素,对后续环境管理和修复策略的选择具有重要意义。本文以上海市某废弃电镀厂作为研究对象,选择污染较为严重的5个区域及1个对照点,采集70个土壤样品和6个地下水样品,测定分析不同深度土壤和地下水中重金属(Hg、Pb、Cd、Cr和As)空间分布特征,结合土壤质地探讨了重金属的迁移影响因素。结果表明,该场地土壤已受到不同程度的重金属污染,Hg、Pb、Cr和Cd的垂向分布均呈现随土壤深度增加而下降趋势,到一定深度时含量达到平稳状态,整体上包气带土壤重金属污染程度远高于饱水带,但是As无明显增减趋势。相关性分析结果表明,土壤粒径是影响重金属垂向迁移的重要因素。根据迁移系数的计算结果,饱水带土壤中Cr的迁移能力相较于包气带更强,说明饱水带中Cr的污染不容忽视。土壤高含量的Cr已造成地下水Cr的严重污染。土壤重金属含量、颗粒组成和水位埋深是影响地下水重金属含量的重要因素。
Contamination and migration characteristics of heavy metals at a typical electroplating site
Heavy metal contamination is a common issue at electroplating sites.It is important to investigate the characteristics and migration of heavy metals in the soil and groundwater for subsequent environmental management and remediation strategies.In this study,a defunct electroplating factory in Shanghai was selected as the research site.A total of 70 soil samples and 6 groundwater samples were collected from five heavily contaminated sites and one control point.The spatial distribution characteristics of heavy metals(Hg,Pb,Cd,Cr,and As)in soil at different depths and groundwater were determined and analyzed,and the influencing factors of heavy metals migration were explored in combination with soil texture.The results showed that the soil at the electroplating plant had been contaminated to varying degrees with heavy metals.The vertical distribution of Hg,Pb,Cr,and Cd in the soil exhibits a decreasing trend with increasing soil profile depth,reaching a stable state at a certain depth.Overall,the levels of heavy metal contamination were much higher in the vadose zone soil than in the saturated zone soil.While,there is no significant trend for As to increase or decrease as the soil profile depth increases.Correlation analysis results indicate that soil particle size is a critical factor affecting the vertical migration of heavy metals.Based on the calculation of migration coefficients,it is evident that the migration capacity of Cr in the saturated zone soil is stronger than in the vadose zone,indicating that the contamination of Cr in the saturated zone should not be underestimated.High levels of Cr in the soil have caused significant contamination of groundwater with Cr.Soil heavy metal content,soil particle composition and groundwater burial depth are important factors that affect the amount of heavy metal in groundwater.

electroplating siteheavy metal contaminationsoilmigration

叶文娟、钱诗颖、吴诗怡、王鸿犇、黄波涛

展开 >

上海市环境科学研究院,上海,200233

电镀场地 重金属污染 土壤 迁移

上海市环境科学研究院创新基金

CX2021180327

2024

环境化学
中国科学院生态环境研究中心

环境化学

CSTPCD北大核心
影响因子:1.049
ISSN:0254-6108
年,卷(期):2024.43(4)
  • 36