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一种羊毛地毯的异味溯源分析

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本文对一种羊毛地毯及其原材料进行气味强度的测试,发现地毯胶和纱线的气味强度贡献最大。对地毯成品及其原材料利用热脱附气相色谱质谱法进行污染物定性定量分析,再根据所释放物质的气味阈值,计算气味活度值。地毯成品中主要致味物质有壬醛、辛醛、十二烷酸、癸醛、十四烷酸、己醛、十五烷酸、乙酸丁酯。其中壬醛、癸醛、己醛主要来源于地毯胶在合成过程中,醛类的单体残留。乙酸丁酯作为地毯胶的溶剂。十二烷酸、十四烷酸、十五烷酸来源于纱线防虫蛀的有机磷农药等成分。纱线材质本身具有极强的吸附性,吸附了环境中的醛类污染物,导致地毯成品中的醛类一部分来源于纱线。利用总气味活度值法,原材料气味污染物贡献率排序为:地毯胶>纱线>白布>网布>绿布。气味污染物的主要来源是地毯胶,约占所有污染物的70%。
Odour traceability analysis of a woolen carpet
In this paper,the odour intensity of a wool carpet and its raw materials was tested,and it was found that the odour intensity of carpet glue and yarn contributed the most.Qualitative and quantitative analysis of total volatile organic compounds was carried out on the finished carpet and its raw materials by thermal desorption gas chromatography-mass spectrometry,and then the odour activity value was calculated based on the odour threshold of the released substances.Substances contributing to the overall odour of finished carpets include nonanal,octanal,dodecanoic acid,decanal,myristic acid,hexanal,pentadecanoic acid,and butyl acetate.Among them,nonanal,decanal,and hexanal are primarily derived from aldehyde monomer residues during carpet glue synthesis.Butyl acetate is used as a solvent for carpet glue.Dodecanoic acid,myristic acid,and pentadecanoic acid originate from ingredients such as organophosphorus pesticides used to mothproof the yarn.The yarn material itself has strong adsorption,absorbing aldehyde pollutants in the environment,resulting in some of the aldehydes in the finished carpet coming from the yarn.Using the total odour activity value method,the odour contribution rate order of raw material pollutants is:carpet glue>yam>white cloth>mesh cloth>green cloth.The main source of odour pollutants is carpet glue,accounting for about 70%of all pollutants.

a wool carpet and its raw materialsodour intensityodour activity

刘实华、裴一朴、卢天旭、关红艳、韩蔚、蔡寒梅、田菲菲、周羽鑫

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中国国检测试控股集团股份有限公司,北京,100024

岛津企业管理(中国)有限公司,北京,100020

北京科技大学天津学院,天津,301830

地毯及其原材料 气味强度 气味活度

中国认证认可协会科技计划(2022)

2022CCAAKY04

2024

环境化学
中国科学院生态环境研究中心

环境化学

CSTPCD北大核心
影响因子:1.049
ISSN:0254-6108
年,卷(期):2024.43(4)
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