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有机磷酸酯的环境行为及其修复技术研究进展

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有机磷酸酯(OPEs)作为阻燃剂和增塑剂已广泛应用于各行各业。OPEs作为添加型的阻燃剂易于释放进入环境造成污染。目前,OPEs作为一类新兴的有机污染物,在世界范围内的各种环境介质中能被广泛检出。本文在对近5年发表的OPEs文献检索和分析的基础上,综述了 OPEs在环境分布、危害、迁移转化和修复技术方面的研究进展。结果表明,OPEs在环境介质中普遍存在,包括土壤、水、沉积物、大气等,可通过环境暴露和饮食进入人体,造成人体健康危害,也对水环境与土壤生态造成影响。在环境中,OPEs存在多种迁移方式,且具备远距离迁移能力,水解是其重要的环境转化行为。芬顿氧化法和光降解法是OPEs较有成效的修复技术。
Environmental behavior and remediation technology of organophosphate esters:A review
Organophosphate esters(OPEs)have been extensively utilized in industries as flame retardants and plasticizers.However,the application of OPEs as additive-type flame retardants makes them prone to being easily released into environments,leading to pollution.OPEs,considered as emerging organic pollutants,have been detected in various environmental media worldwide.This paper provides a comprehensive summary of the recent research findings on the environmental distribution,hazards,transportation,transformation,and remediation technology of OPEs based on an extensive search and analysis of published literatures from the past five years.The findings indicate the pervasive presence of OPEs in various environment,such as soil,water,sediment and air.OPEs not only pose risks to human health through environmental exposure and food sources but also exert detrimental effects on water environment and soil ecology.OPEs exhibit diverse migration pathways within the environment,demonstrating their capacity to disperse over long distances.Hydrolysis is the dominant transformation process for OPEs in natural environments,while Fenton oxidation and photo degradation have been identified as effective remediation technologies for addressing OPEs contamination.

organophosphate estersflame retardantsenvironmental distributiontransportation and transformationremediation technology

李承骏、张浩翔、赵玲、滕应、骆永明、王辰宇

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中国科学院土壤环境与污染修复重点实验室(南京土壤研究所),南京,210008

中国科学院大学,北京,100049

南京信息工程大学长望学院,南京,210044

南京信息工程大学环境科学与工程学院,南京,210044

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有机磷酸酯 阻燃剂 环境分布 迁移转化 修复技术

2024

环境化学
中国科学院生态环境研究中心

环境化学

CSTPCD北大核心
影响因子:1.049
ISSN:0254-6108
年,卷(期):2024.43(12)