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正压罐采样-预浓缩-GC/MS法测定空气中痕量卤代烃

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采用正压罐采样-预浓缩-GC/MS法同时测定空气中16种卤代烃,通过优化试验条件,使16种痕量卤代烃在30 min内实现分离,目标物分别在40 pmol/mol~200 pmol/mol和5 pmol/mol~100 pmol/mol范围内线性良好,方法检出限为4 pmol/mol~55 pmol/mol.标准气体6次测定结果的RSD为1.0%~7.2%,空白样品加标回收率为72.5%~125%.
Determination of Trace Halogenated Hydrocarbons in Air by Canister Collecting-Preconcentration-GC/MS
16 halogenated hydrocarbons in air were simultaneously determined by canister collecting-precon-centration-GC/MS.By optimizing the test conditions,16 trace halogenated hydrocarbons were separated within 30 min.The target objects had good linearity in the range of 40 pmol/mol to 200 pmol/mol and 5 pmol/mol to 100 pmol/mol.The method detection limits were from 4 pmol/mol to 55 pmol/mol.The RSDs of 6 measure-ments of standard gas ranged from 1.0%to 7.2%.The recoveries of blank samples were from 72.5%to 125%.

Halogenated hydrocarbonPreconcentrationGC-MSAmbient air

由希华、张凤菊、李琳、曹方方、李红莉

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山东省生态环境监测中心,山东 济南 250101

卤代烃 预浓缩 气质联用法 环境空气

山东省自然科学基金资助项目

ZR2020ZD21

2024

环境监测管理与技术
江苏省环境监测中心,南京市环境监测中心站

环境监测管理与技术

CSTPCD北大核心
影响因子:1.086
ISSN:1006-2009
年,卷(期):2024.36(2)
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