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全自动固相萃取-气质联用法测定废水中硝基苯类化合物

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采用全自动固相萃取处理废水,气相色谱-质谱联用法测定废水中的15种硝基苯类化合物,通过优化试验条件,使方法在0.100 mg/L~10.0 mg/L范围内线性良好.方法检出限为0.012 μg/L~0.038 μg/L,标准溶液11次测定结果的RSD为1.0%~7.5%.对实际水样做2个质量浓度水平的加标回收试验,平均加标回收率为78.0%~107%.
Determination of Nitrobenzene Compounds in Wastewater by Automatic Solid Phase Extraction-Gas Chromatography-Mass Spectrometry
Fifteen nitrobenzene compounds in wastewater were extracted by automatic solid phase and deter-mined by gas chromatography-mass spectrometry(GC-MS).By optimizing the test conditions,the method had good linearity in the range of 0.100 mg/L to 10.0 mg/L.The method detection limits were from 0.012 μg/L to 0.038 μg/L.The RSDs of 11 measurements of standard solution were from 1.0%to 7.5%.The average spiked recoveries were from 78.0%to 107%when adding two mass concentration levels to practical samples.

Nitrobenzene compoundsSolid phase extractionGC-MSIndustrial wastewater

刘静、曾兴宇、李雪丽、尤菁、周东星

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自然资源部天津海水淡化与综合利用研究所,天津 300192

硝基苯类化合物 固相萃取 气质联用法 工业废水

天津市重点研发计划基金资助项目中央级公益性科研院所基本科研业务费专项基金资助项目

19YFZCSN01330K-JBYWF-2019-QR03

2024

环境监测管理与技术
江苏省环境监测中心,南京市环境监测中心站

环境监测管理与技术

CSTPCD北大核心
影响因子:1.086
ISSN:1006-2009
年,卷(期):2024.36(2)
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