全自动固相萃取-气质联用法测定废水中硝基苯类化合物
Determination of Nitrobenzene Compounds in Wastewater by Automatic Solid Phase Extraction-Gas Chromatography-Mass Spectrometry
刘静 1曾兴宇 1李雪丽 1尤菁 1周东星1
作者信息
- 1. 自然资源部天津海水淡化与综合利用研究所,天津 300192
- 折叠
摘要
采用全自动固相萃取处理废水,气相色谱-质谱联用法测定废水中的15种硝基苯类化合物,通过优化试验条件,使方法在0.100 mg/L～10.0 mg/L范围内线性良好.方法检出限为0.012 μg/L～0.038 μg/L,标准溶液11次测定结果的RSD为1.0％～7.5％.对实际水样做2个质量浓度水平的加标回收试验,平均加标回收率为78.0％～107％.
Abstract
Fifteen nitrobenzene compounds in wastewater were extracted by automatic solid phase and deter-mined by gas chromatography-mass spectrometry(GC-MS).By optimizing the test conditions,the method had good linearity in the range of 0.100 mg/L to 10.0 mg/L.The method detection limits were from 0.012 μg/L to 0.038 μg/L.The RSDs of 11 measurements of standard solution were from 1.0％to 7.5％.The average spiked recoveries were from 78.0％to 107％when adding two mass concentration levels to practical samples.
关键词
硝基苯类化合物/固相萃取/气质联用法/工业废水Key words
Nitrobenzene compounds/Solid phase extraction/GC-MS/Industrial wastewater引用本文复制引用
基金项目
天津市重点研发计划基金资助项目(19YFZCSN01330)
中央级公益性科研院所基本科研业务费专项基金资助项目(K-JBYWF-2019-QR03)
出版年
2024
NETL
NSTL
维普
万方数据