环境监测管理与技术2024,Vol.36Issue(3) :47-50.

太赫兹时域光谱法测定水中重金属离子

Determination of Heavy Metal Ions in Water by Terahertz Time-Domain Spectroscopy

李梅 刘聪 曹毅 梁漫春
环境监测管理与技术2024,Vol.36Issue(3) :47-50.

太赫兹时域光谱法测定水中重金属离子

Determination of Heavy Metal Ions in Water by Terahertz Time-Domain Spectroscopy

李梅 1刘聪 1曹毅 1梁漫春2
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作者信息

  • 1. 清华大学合肥公共安全研究院环境安全研究中心,安徽 合肥 230026
  • 2. 清华大学工程物理系,北京 100083
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摘要

采用太赫兹时域光谱法采集溶液时域数据,经过去噪和时域分析,汞、镉、铜离子溶液分别在频率为1.7THz、0.7THz、1.2THz位置上建立线性模型,得到拟合效果最佳的决定系数,分别为0.969、0.896、0.932.该方法检出限为0.001 mg/L~0.002 mg/L,空白加标样6次测定结果的RSD为2.0%,加标回收率为94.0%~102%.将该方法用于测定某污水处理厂两个进口的实际水样,结果汞离子未检出.

Abstract

Terahertz time-domain spectroscopy was used to collect time-domain data of solutions.After de-noising and time-domain analysis,linear models were established for mercury,cadmium and copper ion solu-tions at frequencies of 1.7 THz,0.7 THz and 1.2 THz respectively,and the determination coefficients with the best fitting effect were 0.969,0.896 and 0.932,respectively.The method detection limit were from 0.001 mg/L to 0.002 mg/L,the RSD of 6 measurements of spiked blank samples was 2.0%,and the recoveries were from 94.0%to 102%.Applying this method in monitoring practical water samples from two inlets of a sewage treat-ment plant,mercury ion was not detected.

关键词

///太赫兹时域光谱法/光学参数计算模型/水质

Key words

Hg/Cd/Cu/Terahertz time-domain spectroscopy/Optical parameter calculation model/Wa-ter quality

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基金项目

安徽省科技重大专项(202003a07020010)

出版年

2024
环境监测管理与技术
江苏省环境监测中心,南京市环境监测中心站

环境监测管理与技术

CSTPCD北大核心
影响因子:1.086
ISSN:1006-2009
参考文献量16
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