环境监测管理与技术2024,Vol.36Issue(3) :59-62.

不同两性复配修饰半碳化纤维对Pb2+的吸附差异

Adsorption Difference of Pb2+by Different Modified Semi-carbon Fiber

郭梦婷 王尹菲 李文斌 邓红艳 阳红
环境监测管理与技术2024,Vol.36Issue(3) :59-62.

不同两性复配修饰半碳化纤维对Pb2+的吸附差异

Adsorption Difference of Pb2+by Different Modified Semi-carbon Fiber

郭梦婷 1王尹菲 1李文斌 1邓红艳 1阳红2
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作者信息

  • 1. 西华师范大学环境科学与工程学院,四川 南充 637000
  • 2. 南充市天然林资源保护工程管理中心,四川 南充 637000
  • 折叠

摘要

以聚丙烯腈为原料制备半碳化纤维(SCF),经化学和生物两性修饰后,再以海藻酸钠进行复配修饰,得到不同的两性复配修饰SCF,通过试验考察其对Pb2+的等温吸附和动力学特征,分析pH值、温度和离子强度对Pb2+吸附的影响.结果表明:供试材料对Pb2+的吸附等温线符合Langmuir和Freundlich模型,最大吸附量(qm)为495.09 mmol/kg~770.56 mmol/kg,两性和两性复配修饰后的SCF对Pb2+的吸附量提高了 1.8%55.6%.pH值升高有利于各供试材料对Pb2+的吸附,离子强度在0.01 mol/L~0.5 mol/L范围内,各供试材料对Pb2+的吸附量呈现先增加后减小的趋势,并在0.1 mol/L时达到最大.热力学参数表明,Pb2+吸附是一个自发、吸热和熵增的过程.

Abstract

Semi-carbon fiber(SCF)prepared from polypropylene hydrocarbon was chemically and biologi-cally modified,and then complexly modified with sodium alginate.Through experiments,the isothermal adsorp-tion and kinetic characteristics of different modified SCFs on Pb2+were investigated,and the effects of pH value,temperature and ionic strength on Pb2+adsorption were analyzed.The results showed that the adsorption isotherm of these test materials conformed to Langmuir and Freundlich models,and the maximum adsorption capacity(qm)was from 495.09 mmol/kg to 770.56 mmol/kg.The adsorption capacity of Pb2+by different modified SCFs increased by 1.8%~55.6%.The increase of pH value was conducive to the adsorption of Pb2+by various test materials.When the ion strength ranged from 0.01 mol/L to 0.5 mol/L,the adsorption capacity of various test materials increased first and then decreased,and reached the maximum at 0.1 mol/L.The thermodynamic parameters indicated that the adsorption of Pb2+was a spontaneous,endothermic and entropy-increasing process.

关键词

半碳化纤维/两性复配修饰/Pb2+/吸附/废水处理

Key words

Semi-carbon fiber/Complex modification/Pb2+/Adsorption/Wastewater treatment

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基金项目

国家自然科学基金资助项目(41271244)

西华师范大学科研业务基金资助项目(18B023)

出版年

2024
环境监测管理与技术
江苏省环境监测中心,南京市环境监测中心站

环境监测管理与技术

CSTPCD北大核心
影响因子:1.086
ISSN:1006-2009
参考文献量19
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