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煤矸石模拟淋滤实验中重金属污染物的释放特征分析

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以新疆某采矿区煤矸石为研究对象,采用动态淋滤实验研究煤矸石中Cu、Cd、Cr、Pb的淋出浓度特征,分析4种金属元素的释放规律,评价其对环境的污染程度,考察淋滤条件对金属元素释放的影响.结果表明,Cu、Cd、Cr、Pb在淋滤前期表现为淋出浓度较高,释放速率较快的特征,随着淋滤时间的延长,各金属元素的淋出浓度降低,释放速率减缓,直至淋滤后期淋出浓度趋于稳定,释放量达到平衡;释放量和淋出率分别表现为Cr>Cu>Pb>Cd和Cd>Cr>Cu>Pb;除Cd外,其余金属元素的释放量随淋滤液pH值的减小和氧化还原电位的增加而升高.
Study on Characteristics of Heavy Metal Pollutants Leaching from Coal Gangue by Simulation Experiment
Taking coal gangue from a mining area in Xinjiang as the research object,dynamic leaching ex-periments were conducted to study the leaching characteristics of Cu,Cd,Cr and Pb in coal gangue.The release patterns of the four elements were analyzed,the pollution level to the environment was evaluated,and the influ-ence of leaching conditions on the release was investigated.The result showed that Cu,Cd,Cr and Pb had the characteristics of high leaching concentration and fast release rate in the early stage of leaching.With the ex-tension of leaching time,the leaching concentration of each element decreased and the release rate slowed down until the leaching concentration tended to be stable and the release amount reached equilibrium in the later stage of leaching.The release amount and leaching rate of each element were Cr>Cu>Pb>Cd and Cd>Cr>Cu>Pb,re-spectively.Except for Cd,the release of other elements increased with the decrease of pH value of leachate and the increase of radox potential.

Heavy metalsDynamic leachingRelease amountPollution indexCoal gangue

张丽、刘伟、黄蕾、阿依古丽·买买提、张雯靖林、马雪琴

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新疆工程学院化学与环境工程学院,新疆 乌鲁木齐 830091

重金属 动态淋滤 释放量 污染指数 煤矸石

新疆维吾尔自治区级大学生创新训练基金资助项目新疆维吾尔自治区高校基本科研业务基金资助项目国家自然科学基金资助项目新疆工程学院博士启动基金资助项目

S202210994036XJEDU2023P135222660332018xgy062105

2024

环境监测管理与技术
江苏省环境监测中心,南京市环境监测中心站

环境监测管理与技术

CSTPCD北大核心
影响因子:1.086
ISSN:1006-2009
年,卷(期):2024.36(3)
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