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西安市典型行业VOCs源成分谱及环境影响

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采用苏玛罐采样-GC/MS法分析西安市家具制造、表面涂装、汽车整车制造和印刷行业VOCs成分谱,计算不同工序VOCs对O3和二次有机气溶胶(SOA)的生成贡献.结果表明:西安市不同行业TVOC排放值为0.332 mg/m3~45.7 mg/m3,涂装行业最高,其次是印刷工序和木质家具制造,汽车软装和印刷覆膜工序较低.木质家具VOCs主要为芳香烃、含氧类有机物和烷烃,随着油性漆替换为水性漆,芳香烃占比下降,含氧类有机物占比上升.汽车喷涂VOCs主要为芳香烃和含氧类有机物,印刷行业VOCs中含氧类有机物占比高.表面涂装排放VOCs对生成O3和SOA贡献最高,印刷行业ROF最小,汽车软装工序RSOA最小.
Source Profiles and Environmental Impact of VOCs in Typical Industries in Xi'an
The source profile of VOCs in furniture manufacturing,surface coating,automobile manufactur-ing and printing industries in Xi'an were analyzed by Suma canister collecting-GC/MS.The contribution of VOCs from different processes to the generation of O3 and secondary organic aerosol(SOA)was calculated.The re-sults showed that TVOC mass concentration from different industries in Xi'an was from 0.332 mg/m3 to 45.7 mg/m3,with the highest in painting industry,followed by printing process and furniture manufacturing,and the lowest in automobile decoration and laminating process.VOCs from furniture manufacturing were main-ly aromatic hydrocarbons,oxygen-containing organic matter and alkane.With the substitution of oil-based paint for water-based paint,the proportion of aromatic hydrocarbons decreased and the proportion of oxygen-containing organic matter increased.VOCs from automobile spray were mainly aromatic hydrocarbons and oxygen-containing organic matter.The proportion of oxygen-containing organic matter in VOCs from printing industry was high.VOCs from surface coating contributed the most to the generation of O3 and SOA.ROF of VOCs from printing in-dustry was the smallest.RSOA of VOCs from automobile decoration process was the smallest.

VOCsTypical industrySource profileEnvironmental impactXi'an

陈妙、薛兴钊、李顺姬、曹泽磊、孟小兰、党小庆、黄宇广

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西安市环境保护科学研究院,陕西 西安 710061

西安建筑科技大学,陕西 西安 710200

挥发性有机物 典型工业 谱库 环境影响 西安市

国家重点研发计划基金资助项目陕西省重点研发计划基金资助项目

2017YFC02122002024SF-YBXM-569

2024

环境监测管理与技术
江苏省环境监测中心,南京市环境监测中心站

环境监测管理与技术

CSTPCD北大核心
影响因子:1.086
ISSN:1006-2009
年,卷(期):2024.36(3)
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