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纳米铂-石墨烯修饰电极测定氧氟沙星

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采用多电位阶跃法将铂纳米颗粒(PtNPs)沉积于石墨烯(Gr)修饰的玻碳电极(GCE)表面,制备PtNPs/Gr/GCE修饰电极,用于测定氧氟沙星(OFL),并考察OFL在该修饰电极上的电化学行为.通过优化试验条件,方法分别在0.75 µmol/L~50 µmol/L 和 75 µmol/L~250 µmol/L 范围内线性良好,检出限为 0.02 μmol/L.将 PtNPs/Gr/GCE 修饰电极用于实际自来水和地下水样品测定,结果均为未检出,加标回收率为95.3%~102%,RSD为1.0%~2.8%.
Determination of Loxacin by Platinum Nanoparticles-Graphene Modified Electrode
A method for the determination ofloxacin(OFL)by PtNPs/Gr/GCE modified electrode prepared by depositing platinum nanoparticles(PtNPs)on the surface of glassy carbon electrode(GCE)modified with gra-phene(Gr)was established using multi-potential step method.The electrochemical behavior of OFL on the modi-fied electrode was studied.By optimizing the experimental conditions,the method had good linearity in the ran-ges of 0.75 μmol/L~50 μmol/L and 75 μmol/L~250 μmol/L.The detection limit was 0.02 μmol/L.Apply-ing PtNPs/Gr/GCE modified electrode in determining practical tap water and groundwater samples,the results were not detected.The spiked recoveries were from 95.3%to 102%,and the relative standard deviations were from 1.0%to 2.8%.

OfloxacinPlatinum nanoparticlesGrapheneDPVModified electrodeWater quality

冯丽敏、薛强、李文博、许伟伟、贺小桐、李文婷

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自然资源部国土(耕地)生态监测与修复工程技术创新中心,江苏省地质调查研究院,江苏 南京 210018

中国地质大学(北京)水资源与环境工程北京市重点实验室,北京 100083

氧氟沙星 铂纳米颗粒 石墨烯 差分脉冲伏安法 修饰电极 水质

2024

环境监测管理与技术
江苏省环境监测中心,南京市环境监测中心站

环境监测管理与技术

CSTPCD北大核心
影响因子:1.086
ISSN:1006-2009
年,卷(期):2024.36(6)