首页|西北石化区周围毒害类空气污染物污染特征及健康风险评价

西北石化区周围毒害类空气污染物污染特征及健康风险评价

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采用SUMMA罐、 活性炭吸附及玻璃纤维滤膜富集3种方式,于2014年12月对西北地区3个代表性炼化生产基地周围环境空气收集样品,并采用气相色谱-质谱联用、 气相色谱法及高效液相色谱法3种方法,对13种典型毒害类物质进行分析,以研究其污染特征和人群健康风险.结果表明,3个石化区周围环境空气中8种毒害类物质普遍检出,检出率超过80%;石化区苯系物、1,3-丁二烯、 对二氯苯、 苯并[a]芘平均质量浓度范围分别为48.01~182.75μg·m-3、6.28~7.95μg·m-3、5.53~12.62μg·m-3、7.03~36.08 ng·m-3.其中,苯并[a]芘超标最为严重,日均浓度超二级标准限值1.8~13.4倍,苯、 甲苯、 二甲苯也存在不同程度超标现象.3个石化区苯并[a]芘、1,3-丁二烯非致癌健康风险均已超出可接受的风险水平,兰州石化区周围人群遭受苯的非致癌不良影响风险也较高.与此同时,苯、 乙苯、 苯乙烯、1,3-丁二烯、 对二氯苯、 苯并[a]芘的致癌风险均超出了可接受的范围,其中苯、1,3-丁二烯、 对二氯苯的致癌风险最为显著.
Pollution Characteristics and Health Risk Assessment of Hazardous Air Pollutants in the Surroundings of Three Petrochemical Industries in Northwest China
The samples in the surroundings of three representative petrochemical industries in Northwest China were collected by summa canister/ adsorption using activated carbon/ glass fiber filter, and then they were analyzed for 13 hazardous air pollutants by gas chromatography-mass spectrometry/ gas chromatograph/ high performance liquid chromatography. The pollution characteristics and human health risk of hazardous air pollutants were discussed. The results showed that 8 hazardous air pollutants existed in the surroundings of all petrochemical industries. The detection frequency for 8 hazardous air pollutants exceeded 80% . The ranges of the average concentrations of benzene series ( BTEX), 1,3-butadiene, 1,4-dichlorobenzene, benzo [ a] pyrene were 48. 01- 182. 75μg·m - 3 , 6. 28-7. 95 μg·m - 3 , 5. 53-12. 62 μg·m - 3 and 7. 03-36. 08 ng·m - 3 . Daily average concentration of benzo[a]pyrene was 1. 8-13. 4 times higher than the limit of national standard level-Ⅱ, and those of benzene, toluene and xylene were also over their limits of standard to different degrees. The non-carcinogenic risks of benzo[ a] pyrene and 1,3-butadiene were beyond acceptable levels around the three petrochemical industries in Northwest China. Meanwhile, the non-carcinogenic health impact of benzene was appreciable on the exposed population of Lanzhou petrochemical industrial area. The carcinogenic risks of benzene, ethylbenzene, styrene, 1,3-butadiene, 1,4-dichlorobenzene and benzo[a]pyrene were beyond acceptable levels. At the same time, the carcinogenic risks of benzene, 1,3-butadiene and 1,4-dichlorobenzene were significantly higher than their acceptable ranges recommended by US EPA.

petrochemical industry in Northwest Chinahazardous air pollutantsVOCspollution characteristicshealth risk assessmentcarcinogenic risknon-carcinogenic risk

许亚宣、李小敏、于华通、董林艳、赵玉婷、姚懿函、邹广迅、张新民

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中国环境科学研究院,北京 100012

北京中环博宏环境资源科技有限公司,北京 100012

西北石化区 毒害类空气污染物 挥发性有机物(VOCs) 污染特征 健康风险评价 致癌风险 非致癌风险

区域和行业重大发展战略环境评价项目

2110203

2017

环境科学
中国科学院生态环境研究中心

环境科学

CSTPCDCSCD北大核心EI
影响因子:1.913
ISSN:0250-3301
年,卷(期):2017.38(7)
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