首页|不同施肥方式下紫色土N2O与NOx的排放特征

不同施肥方式下紫色土N2O与NOx的排放特征

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利用紫色土长期施肥试验平台,采用静态箱-气相色谱法开展紫色土"冬小麦-夏玉米"轮作系统N2 O和NOx排放的连续两周年(2014年11月~2016年9月)定位观测.研究了氮肥总量相同条件下的常规氮磷钾化肥(NPK)、 猪厩肥(OM)、 秸秆还田配施氮磷钾化肥(RSDNPK)、 猪厩肥配施氮磷钾化肥(OMNPK)和氮磷钾化肥配合硝化抑制剂(DCDNPK)等施肥方式对N2 O和NOx排放的影响,短期不施肥处理(CK)作为排放系数计算的对照.结果表明,所有施肥方式下紫色土N2 O排放峰均出现在施肥初期和大降雨过程期;NOx排放过程与N2 O类似,排放峰出现在施肥初期,但强降雨期未出现明显排放峰.NPK、OM、RSDNPK、OMNPK和DCDNPK处理的N2 O年均累积排放量分别为:1.35、4.38、1.43、2.46、0.92 kg?hm-2,排放系数分别为:0.33%、1.41%、0.36%、0.73%、0.18%;相应处理的NOx年均累积排放量分别为:0.11、0.38、0.10、0.27、0.04 kg?hm-2,排放系数分别为:0.03%、0.13%、0.03%、0.09%、0.01%.较常规化肥,增加有机物料如施用猪厩肥和猪厩肥配施氮磷钾肥分别显著增加226%和83%的N2 O排放(P<0.01),同时NOx排放分别显著增加262%和157%(P<0.01);常规化肥配合硝化抑制剂(DCDNPK)使用减少32%的N2 O排放和62%的NOx排放(P<0.01),秸秆还田配施氮磷钾肥对N2 O排放略有增加(P>0.05),NOx排放略有减少(P>0.05).统计分析进一步表明,土壤无机氮含量是N2 O和NOx二者排放的主控因子,而土壤孔隙充水率与温度分别作为N2 O与NOx各自排放的主控因子之一.
Characteristics of N2 O and NOx Emissions from Purple Soil Under Different Fertilization Regimes
N2 O and NOx emissions from a winter wheat-summer maize rotation system in purple soil were measured on a long-term fertilization platform of purple soil for two consecutive cropping years (from November 2014 to September 2016) by using a closed-chamber and gas chromatography-based system. Chemical fertilizer (NPK), pig manure (OM), incorporation of crop residues plus synthetic NPK fertilizer ( RSDNPK), pig manure plus synthetic NPK fertilizer ( OMNPK), and nitrification inhibitor with NPK fertilizer (DCDNPK) under the same rate of total nitrogen were involved in monitoring N2 O and NOx emissions. Short-term fertilizer-free treatment (CK) was used as a control for emission coefficient calculation. The results showed that N2 O emission peaks appeared in the early stage of fertilization and in the period of heavy rainfall for all fertilization regimes. The NOx emission process was similar to that of N2 O, in that emission peaks appeared at the early stage of fertilization, yet no obvious emission peaks were observed during heavy rainfall. The annual cumulative emissions of N2 O from NPK, OM, RSDNPK, OMNPK, and DCDNPK were 1. 35, 4. 38, 1. 43, 2. 46, and 0. 92 kg?hm - 2 , respectively, and the emission coefficients were 0. 33% , 1. 41% , 0. 36% 0. 73% , and 0. 18% . The annual emissions of NOx from NPK, OM, RSDNPK, OMNPK, and DCDNPK were 0. 11, 0. 38, 0. 10, 0. 27, and 0. 04 kg?hm - 2 , respectively, and the cumulative emission coefficients were 0. 03% , 0. 13% , 0. 03% , 0. 09% , and 0. 01% . Amendment of organic material was the main stimulator for N2 O and NOx emissions, as they significantly increased 226% and 262% (for OM) and 83% and 157% ( for OMNPK), respectively ( P < 0. 01), compared with conventional synthetic fertilizers. The application of synthetic fertilizers combined with nitrification inhibitor (DCDNPK) significantly reduced N2 O emissions 32% and NOx emissions 62% (P <0. 01), whereas straw returning with NPK application increased N2 O emissions 6% and reduced NOx emissions 5% ( P > 0. 05). Furthermore, statistical analyses showed that soil inorganic N content was the main regulating factor of N2 O and NOx emissions together, whereas soil water-filled pore space (WFPS) and temperature were the respective main regulating factors of N2 O and NOx emissions individually.

fertilization regimecumulative emissionemission coefficientregulation conditionsoptimal fertilization

胡磊、刘韵、朱波

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中国科学院成都山地灾害与环境研究所,成都 610041

中国科学院大学,北京 100049

中国科学院山地表生过程与生态调控重点实验室,成都 610041

施肥方式 累积排放 排放系数 控制条件 合理施肥

国家自然科学基金国家重点基础研究发展规划(973)项目

412713212012CB417101

2017

环境科学
中国科学院生态环境研究中心

环境科学

CSTPCDCSCD北大核心EI
影响因子:1.913
ISSN:0250-3301
年,卷(期):2017.38(8)
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