首页|溶解性有机质的光谱特征及其对土壤吸附β-HCH的影响

溶解性有机质的光谱特征及其对土壤吸附β-HCH的影响

Spectral characteristics of dissolved organic matter and its effects on the adsorption of β-HCH in the soil

扫码查看
通过考察4种不同来源的溶解性有机质(Dissoived Organic Matter,DOM)的紫外-可见光谱和三维荧光光谱特征,分析DOM的组分及结构,研究它们对β-HCH在土壤中的吸附影响.结果表明,不同来源的DOM具有不同的组成结构,对β-HCH在土壤中的吸附有不同影响.光谱特征分析结果显示,DOM芳香性和疏水性强弱顺序为:营养土>A土>淤泥>B土.研究显示,在去除DOM条件下,土壤对β-HCH吸附量增加,即内源DOM的存在均抑制了土壤对β-HCH的吸附能力,吸附能力与内源DOM组分的亲疏水性有关.外源DOM均能促进土壤对β-HCH的吸附能力,但来源不同,促进土壤吸附β-HCH的能力不同,其吸附能力的强弱排序为:淤泥DOM>营养土DOM>B土DOM,这是由各土壤DOM的不同组分及不同的疏水性导致的.
The composition and structure signatures of four dissolved organic matter (DOM) were analyzed with Ultraviolet-visible(UV-Vis) and threedimensional fluorescence spectroscopy characteristics,and their effects on the adsorption ofβ-HCH in the soil were studied.The results showed that,DOM extracted from different soil has different composition and effect on the adsorption ofβ-HCH in the soil.According to the spectral characteristics,aromaticity and hydrphobicity of DOM were in order of nutritional soil>sample A>sludge>sample B.Under the condition of removing DOM,adsorption of β-HCH in the soil,and the adsorption capacity was related with the hydrophily and hydrphobicity of DOM.The adsorption ability ofβ-HCH in the soil can be promoted by exogenous DOM.Because of the different component and hydrophobicity of DOM,the effects on the adsorption ofβ-HCH in the soil were different,the adsorption ofβ-HCH in the soil was in order of sludge>nutrition soil>sample B.

dissolved organic matterβ-HCHadsorptionsoil

龚香宜、徐威、何炎志

展开 >

武汉科技大学资源与环境工程学院,武汉430081

溶解性有机质 β-HCH 吸附作用 土壤

国家自然科学基金

41102218

2017

环境科学学报
中国科学院生态环境研究中心

环境科学学报

CSTPCDCSCD北大核心
影响因子:1.645
ISSN:0253-2468
年,卷(期):2017.37(1)
  • 7
  • 8