首页|唐山市臭氧污染特征及生成敏感性分析

唐山市臭氧污染特征及生成敏感性分析

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基于唐山市2014-2022年大气污染物与气象观测数据,分析了唐山市O3污染时空分布特征,并运用广义相加模型(GAM)分析了气象要素对O3浓度的影响。同时,基于WRF-CAMx模型绘制的EKMA曲线讨论了唐山市O3生成敏感性,并提出旨在提升环境效益的前体物最优减排比例。结果表明:①唐山市O3月均浓度呈倒"V"型变化趋势,在6月出现高值,12月出现低值,在季节变化上整体表现为夏季>春季>秋季>冬季;日变化呈"单峰型"的变化趋势,O3浓度峰值与谷值分别出现在15:00、6:00;空间分布上,O3浓度自东南沿海向北递减,具体表现为东南部沿海区域>中心城区>东北部山区>北部区域。②影响唐山市O3浓度的气象要素显著性大小为温度>太阳辐射强度>相对湿度>大气边界层高度,在边界层高度与相对湿度较低、温度与地表太阳辐射较高时易出现O3污染。③在O3控制策略方面,唐山市中心城区及周边区域以VOCs控制区为主,在西北部、东南部与东北部区域以VOCs与NOx协同控制区为主,对处于VOCs与NOx协同控制区的区域,建议VOCs和NOx的削减比例为1∶1,对处于VOCs控制型的区域,建议VOCs和NOx的削减比例为1。5∶1,以实现环境效益的最大化。
Research on meteorological impact factors and generation sensitivity of O3 in Tangshan
Based on the atmospheric pollutant and meteorological observation data of Tangshan City from 2014 to 2022,this study analyzed the spatial and temporal distribution characteristics of O3 pollution in Tangshan City,and used the generalized additive model(GAM)to analyze the impact of meteorological factors on O3 concentration.The EKMA curve drawn based on the WRF-CAMx model discussed the sensitivity of O3 generation in Tangshan City,and proposed the optimal emission reduction ratio of precursor substances to improve environmental benefits.The results showed that① the monthly average concentration of O3 in Tangshan City showed an inverted"V"trend,with high values in June and low values in December,and overall performance in seasonal changes was summer>spring>autumn>winter;the daily variation showed a"single peak"trend,with peak and valley values of O3 concentration occurring at 15:00 and 6:00 respectively;the spatial distribution of O3 concentration decreased from the southeastern coastal area to the north,specifically in the southeastern coastal area>central urban area>northeastern mountainous area>northern area.②The significance of meteorological factors affecting O3 concentration was temperature>solar radiation intensity>relative humidity>atmospheric boundary layer height,and O3 pollution was prone to occur when the boundary layer height and relative humidity were low and the surface solar radiation was high.③In terms of O3 control strategies,the central urban area and surrounding areas of Tangshan City were dominated by VOCs control areas,while the northwest,southeast,and northeast regions were dominated by VOCs and NOx collaborative control areas.For areas under VOCs and NOx collaborative control,it was recommended that the reduction ratio of VOCs and NOx be 1∶1,while for areas under VOCs control,it was recommended that the reduction ratio of VOCs and NOx be 1.5∶1 to maximize environmental benefits.

TangshanO3temporal and spatial distributionmeteorological elementsgeneralized additive model(GAM)WRF-CAMxsensitivity analysis

方承懿、王晓琦、蔡斌、王传达、蒋凯

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北京工业大学环境科学与工程学院,区域大气复合污染防治北京市重点实验室,北京 100124

唐山市 O3 时空分布 气象要素 广义相加模型(GAM) WRF-CAMx 敏感性分析

2025

环境科学学报
中国科学院生态环境研究中心

环境科学学报

北大核心
影响因子:1.645
ISSN:0253-2468
年,卷(期):2025.45(1)