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沈阳市环境空气中PM2.5与O3关联性分析

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以东北地区典型城市沈阳市为例,运用多种监测手段,分析了沈阳市环境空气中PM2.5和O3 的浓度及其组分的关联性,以期为PM2.5与O3 的协同控制提供技术支撑.结果表明:春季和秋季O3 最大8h滑动平均值浓度随PM2.5日均浓度的升高而呈现先升高后降低的趋势;夏季两者浓度在 0.01 水平上呈显著正相关;冬季两者浓度在 0.01 水平上呈显著负相关关系.春季和秋季昼间PM2.5浓度越高,O3 小时浓度上升速率越快,夜间PM2.5浓度越高,O3 小时浓度下降速率越快.夏季昼间、夜间O3 小时浓度均随PM2.5浓度的升高而升高.冬季昼间、夜间O3 小时浓度均随PM2.5浓度的升高而降低.随光化学活性水平的增强,PM2.5和O3 的相关性逐渐减弱.中度光化学活性水平下,白天PM2.5/CO的值明显高于其他光化学活性水平,但中度、重度光化学水平下,白天PM2.5/CO的变化速率明显大于低、轻度光化学水平.且PM2.5/CO的峰值与O3 峰值具有高度一致性.夏、秋2 季SNA(SO42-、NO3-、NH4+)在PM2.5中所占比例与Ox 在0.01 水平上呈显著正相关.春、夏、秋季SOA在PM2.5中所占比例与Ox 在 0.01 水平上呈显著正相关.
Study on the correlation between PM2.5 and O3 in ambient air in Shenyang
Taking Shenyang,a typical city in Northeast China,as an example,this study analyzes the correlation between the concentrations and components of PM2.5 and O3 in the ambient air of Shenyang by using various monitoring methods,in order to provide technical support for the collaborative control of PM2.5 and O3.The results show that the maximum 8-hour sliding average concentration of O3 in spring and autumn increases first and then decreases with the increase of PM2.5 average daily concentration.In summer,the concentrations of both were positively correlated at 0.01 level.In winter,there was a significant negative correlation between the two concentrations at 0.01 level.The higher the PM2.5 concentration in spring and autumn,the faster the O3 hourly concentration increases;The higher the PM2.5 concentration at night,the faster the O3 hourly concentration decreases.In summer,the hourly O3 concentration increases with the increase of PM2.5 concentration.In winter,the hourly O3 concentration decreased with the increase of PM2.5 concentration.With the increase of photochemical activity level,the correlation between PM2.5 and O3 gradually decreases.The change rate of PM2.5/CO at moderate and severe photochemical activity levels was significantly higher than that at low and mild photochemical activitylevels.The peak value of PM2.5/CO is highly consistent with that of O3.The proportion of SNA(SO42-,NO-3,NH+4)in PM2.5 in summer and autumn was significantly positively correlated with Ox at 0.01 level.The proportion of SOA in PM2.5 in spring,summer and autumn was significantly positively correlated with Ox at 0.01 level.

PM2.5O3cooperative controlparticulate matter component

王男、孙学斌、刘闽、李艳、周游

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辽宁省沈阳生态环境监测中心,辽宁 沈阳 110136

沈阳理工大学 环境与化学工程学院,辽宁 沈阳 110136

PM2.5 O3 协同控制 颗粒物组分

2021年辽宁省自然基金资助计划项目

2021-MS-079

2024

环境生态学

环境生态学

CSTPCD
ISSN:
年,卷(期):2024.6(8)
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