火箭推进2024,Vol.50Issue(5) :75-81.DOI:10.3969/j.issn.1672-9374.2024.05.007

超分子甲基肼凝胶燃料流变性能研究

Rheological properties of supramolecular methylhydrazine gel fuel

孙晓涵 宋隆 左向春 孙海云 刘江强 童坤
火箭推进2024,Vol.50Issue(5) :75-81.DOI:10.3969/j.issn.1672-9374.2024.05.007

超分子甲基肼凝胶燃料流变性能研究

Rheological properties of supramolecular methylhydrazine gel fuel

孙晓涵 1宋隆 1左向春 1孙海云 1刘江强 1童坤1
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作者信息

  • 1. 北京航天试验技术研究所,北京 100074
  • 折叠

摘要

流变性能研究是凝胶推进剂研究的一项重要内容,其结果可为推进剂的雾化、燃烧等性能研究提供基础.超分子甲基肼凝胶燃料内部以氢键等非共价相互作用力作为支点,形成网状结构,其流变性能与胶凝剂含量和温度条件密切相关.实验结果表明,胶凝剂含量越高,体系越稳定.胶凝剂质量分数为1.2%时,超分子甲基肼凝胶燃料可在得到最高的能量性能的同时保证稳定性.随着体系温度的升高,形成凝胶网络结构的氢键作用力会变弱,对分子的限制作用也会减弱.体现在流变性能上,就是随着温度的增加,体系黏度和剪切应力降低;在达到50℃时,超分子甲基肼凝胶燃料已处于凝胶-溶液转变的临界点.超分子甲基肼凝胶燃料还具有剪切恢复性,在经历10次剪切过程后,黏度仅有少量降低.

Abstract

The study of rheological properties is an important content of gel propellant research,and its results can provide a basis for the study of atomization and combustion properties of propellant.The interior of supramolecular methylhydrazine gel propellant is supported by non-covalent interaction forces such as hydrogen bonds,forming a network structure,and its rheological properties are closely related to the content of gelling agent and temperature conditions.The experimental results show that the higher the content of gelling agent,the more stable the system is.When the mass fraction of gelling agent is 1.2%,supramolecular methylhydrazine gel fuel can obtain the highest energy performance and ensure stability at the same time.With the increase of system temperature,the hydrogen bonding force forming gel network structure will weaken,and the limiting effect on molecules will also weaken.Reflected in the rheological properties,the viscosity and shear stress of the system decrease with the increase of temperature.When it reaches 50 ℃,supramolecular methylhydrazine gel fuel is at the critical point of gel-solution transition.Supramolecular methylhydrazine gel fuel also has shear recovery,and its viscosity decreases only a little after 10 shear processes.

关键词

超分子/甲基肼/凝胶推进剂/非共价相互作用力/流变性能

Key words

supermolecule/methylhydrazine/gel propellant/noncovalent interaction force/rheological property

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出版年

2024
火箭推进
航天推进技术研究院

火箭推进

CSTPCDCSCD北大核心
影响因子:0.311
ISSN:1672-9374
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