首页|Nb元素对高熵合金涂层组织与力学性能的影响

Nb元素对高熵合金涂层组织与力学性能的影响

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利用激光熔覆技术在Q235基体表面制备CoCrFeNiTi0.8Nby(y = 0.25,0.5,0.75,1.0)涂层.采用光学显微镜、X射线衍射仪、扫描电子显微镜、能谱分析仪等方法分析涂层的相结构和微观组织等;用显微维氏硬度计、摩擦磨损试验机测试涂层的硬度与耐磨性能.结果表明,组织中呈现典型的树枝晶结构,加入Nb元素,涂层微观组织的尺寸减小,增加Nb元素含量时,高熵合金涂层的晶体结构由体心立方相(body-centered cubi,BCC)、少量的面心立方相(face-centered cubic,FCC)和Fe2(Ti,Nb)型的Laves相组成;在细晶强化、固溶强化和第二相强化的共同作用下提高了涂层的显微硬度;中间相的存在一定程度上可以阻碍犁削切削过程的进行,进而提高了涂层的耐磨性能;CoCrFeNiTi0.8Nb0.75 涂层的硬度和耐磨性最好,硬度为710 HV,约为基体的4倍,涂层的磨损量最小,磨痕较为平整.
Effect of Nb components on the microstructure and mech-anical properties of high-entropy alloy coatings
CoCrFeNiTi0.8Nby(y = 0.25,0.5,0.75,1.0)coatings were prepared on the surface of Q235 steel using laser cladding.The phase structure and microstructure of the coat-ings were analyzed by optical microscope(OM),X-ray dif-fractometer(XRD),scanning electron microscope(SEM)and energy dispersive spectroscopy(EDS).The hardness and wear resistance of the coatings were tested by micro-Vickers hard-ness tester and friction wear tester.The results show that the microstructure shows a typical dendritic crystal structure,and the addition of Nb elements decreases the size of the grains;by increasing the content of Nb elements,the crystal structure of the high-entropy alloy coatings consists of BCC phases,a small amount of FCC phases,and Fe2(Ti,Nb)-type Laves phases;the microhardness of the coatings is improved by the combined ef-fect of fine-grained reinforcement,solid solution strengthening,and the strengthening of the second phase;The presence of the intermediate phase can hinder the plough cutting process to a certain extent,which improves the wear resistance of the coat-ing;CoCrFeNiTi0.8Nb0.75 coating has the best hardness and wear resistance,the hardness of 710 HV,about 4 times that of the substrate,and the coating has the smallest amount of abra-sion,and the abrasion marks are relatively flat.

laser claddingHigh-entropy alloymicro-structurewear resistancemechanical properties

王永东、宫书林、常萌阳、王金宇、任远达、景宗浩

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黑龙江科技大学, 哈尔滨, 150022

激光熔覆 高熵合金 微观组织 耐磨性 力学性能

黑龙江省教育厅基本科研业务费资助项目黑龙江科技大学研究生创新科研一般项目

2020-KYYWF-0699YJSCX2022-215HKD/YJSCX2023-132HKD

2024

焊接学报
中国机械工程学会 中国机械工程学会焊接学会 机械科学研究院哈尔滨焊接研究所

焊接学报

CSTPCD北大核心
影响因子:0.815
ISSN:0253-360X
年,卷(期):2024.45(3)
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