首页|钎焊温度对BNi-2非晶钎料钎焊1Cr18Ni9Ti不锈钢组织和性能的影响

钎焊温度对BNi-2非晶钎料钎焊1Cr18Ni9Ti不锈钢组织和性能的影响

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采用BNi-2 非晶钎料成功钎焊了 1Cr18Ni9Ti不锈钢,通过扫描电子显微镜及能谱仪对不同钎焊温度下钎焊接头的界面微观组织进行了表征及分析,并对钎焊接头的抗剪强度进行了测试,探究了钎焊温度对接头界面组织及力学性能的影响.结果表明钎焊接头的界面微观组织从钎缝中心到母材可以被分为 3个区域,钎焊温度为 1050℃时钎缝区主要为Ni基固溶体+Cr-B相,扩散区分布有Fe-Ni固溶体及细小条状的σ-FeCr相,晶间渗入区中奥氏体晶间处分布着σ-FeCr相及Cr-B相.随着钎焊温度的升高,B元素扩散速度不断加快,Cr-B相的晶间渗入程度加剧;钎缝中心的块状Cr-B相逐渐减小直至1150℃时消失,钎缝区组织均匀化.在温度的作用下,钎缝宽度呈现先减小后增大的趋势.而接头的抗剪强度呈先上升后下降的趋势;最大抗剪强度出现在 1050℃时,约 265 MPa;而接头的断裂形式主要以韧性断裂为主.利用阿伦尼乌斯方程得到了B原子的扩散活化能为8.18×104×n J/mol,n为时间指数.
Effect of brazing temperature on microstructure and properties of 1Cr18Ni9Ti stainless steel brazed by amorphous BNi-2 filler
1Cr18Ni9Ti stainless steel was successfully brazed with BNi-2 amorphous filler.The interfacial microstructure of brazed joints at different brazing temperatures was characterized and analysed by scanning electron microscope and energy dispersive spectrometer,and the shear strength of brazed joints was tested.The effect of brazing temperatures on the interfacial microstructure and mechanical properties of the joints was investigated.The results showed that the interfacial microstructure of brazed joints could be divided into three regions from the brazing seam centre to the base material,when the brazing temperature was 1050℃,the brazing seam region was mainly Ni-based solid solutions+Cr-B phases;the diffusion region was distributed with Fe-Ni solid solution and fine strips of σ-FeCr phase;and in the intergranular infiltration region,the austenite grain boundaries were distributed with the σ-FeCr phases and the Cr-B phases.As the brazing temperature increased,the diffusion rate of B element was accelerated and the intergranular infiltration of Cr-B phases was intensified;the massive Cr-B phases in the centre of the braze were gradually reduced until they disappeared at 1150℃,and the microstructure of the braze area was homogenised.Under the effect of temperature,the width of the brazed joints showed a tendency to decrease and then increase.And the shear strength of the joints showed a tendency of increasing and then decreasing;the maximum shear strength appeared at 1050℃,about 265 MPa;and the fracture form of the joints was mainly dominated by ductile fracture.Using the Arrhenius equation the diffusion activation energy of the B atom was obtained as 8.18×104×n J/mol,with n being the time index.

brazingamorphous fillermicrostructurestainless steeldiffusion activation energy

田晓羽、张志伟、周晨、赵连清、田洋光、付伟、宋晓国

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北京控制工程研究所,北京,100190

哈尔滨工业大学材料结构精密焊接与连接全国重点实验室,哈尔滨,150001

山东船舶技术研究院,威海,264209

钎焊 非晶钎料 微观组织 不锈钢 扩散激活能

国家自然科学基金国家自然科学基金山东省"泰山学者"建设工程专项

5217530752105330tsqn201812128

2024

焊接学报
中国机械工程学会 中国机械工程学会焊接学会 机械科学研究院哈尔滨焊接研究所

焊接学报

CSTPCD北大核心
影响因子:0.815
ISSN:0253-360X
年,卷(期):2024.45(6)
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