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钻削热历史对CF/PEEK材料性能影响规律研究

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碳纤维增强聚醚醚酮(CF/PEEK)是一种高性能的热塑性复合材料,在航空制造业有着广阔的应用前景.此材料在制孔及降温过程中,孔周在不同轴-径向位置存在显著的热历史差异,而降温过程与热塑性树脂再结晶过程密切相关.为进一步明确钻削热对孔周性能带来的影响,本文开展钻削热对碳纤维/PEEK(CF/PEEK)树脂性能影响规律研究.首先模拟孔周热历史对PEEK样件进行预处理后测定材料力学参数;其次引入纤维参数,推导出CF/PEEK的材料力学参数并测定结晶度;最后建立降温速率与材料性能的关联关系,阐明了钻削热对CF/PEEK力学性能的影响.发现随着降温速率降低,较低的冷却速率对树脂性能有增益影响,PEEK基体结晶度会升高,拉伸强度增大,而在快速冷却下材料的拉伸强度及弹性模量最低,分别为65.32 MPa和3.3 GPa.
Research on Effect of Drilling Thermal History on Properties of CF/PEEK Materials
Carbon fiber reinforced polyether ether ketone(CF/PEEK)is a kind of high performance thermoplastic composite material,which has broad application prospects in aviation manufacturing industry.There are significant differences in thermal history between the different axial and radial positions of the hole circumference in the process of hole making and cooling process of this material,and the cooling process is closely related to the recrystallization process of thermoplastic resin.In order to further clarify the influence of drilling heat on the performance around the hole,the effect of drilling heat on properties of CF/PEEK resin was studied in this paper.Firstly,the PEEK sample was pretreated by simulating the thermal history around the hole,and then the material mechanical parameters were measured.Secondly,the fiber parameters were introduced,the material mechanical parameters of CF/PEEK were deduced and the crystallinity was determined.Finally,the relationship between the cooling rate and the material properties was established,and the effect of drilling heat on the mechanical properties of CF/PEEK was clarified.It is found that as the cooling rate decreases,the lower cooling rate has a beneficial effect on the resin properties,the crystallinity of the PEEK matrix will increase,and the tensile strength will increase.While the tensile strength and elastic modulus of the material are the lowest under rapid cooling,which are 65.32 MPa and 3.3 GPa,respectively.

CFRPThermoplasticityThermal effectsMechanical propertiesCrystallinity

史建猛、邱建平、李丰辰、齐振超、张斌

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中航西安飞机工业集团股份有限公司,西安 710089

南京航空航天大学,南京 210016

碳纤维复合材料 热塑性 热影响 力学性能 结晶度

2024

航空制造技术
北京航空制造工程研究所

航空制造技术

CSTPCD北大核心
影响因子:0.403
ISSN:1671-833X
年,卷(期):2024.67(7)
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