首页|Si合金化对10Cr铁/马钢在液态铅铋共晶环境中的液态金属脆化敏感性的影响

Si合金化对10Cr铁/马钢在液态铅铋共晶环境中的液态金属脆化敏感性的影响

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铁素体/马氏体钢是第四代液态铅铋冷却快堆燃料包壳和其他堆内构件的重要候选结构材料.Si合金化是目前国内外改善铁/马钢在铅铋环境中的腐蚀性能的关键技术手段,但Si的加入对应力腐蚀开裂敏感性(即"液态金属脆化")的影响规律还有待深入研究.本文通过开展慢应变速率拉伸实验,对比研究了 4 种不同Si含量对 10Cr铁素体/马氏体钢在 350℃、贫氧和饱和氧铅铋以及氩气环境中的拉伸断裂行为,并结合断口分析,确定了Si对液态金属脆化敏感性的影响规律.结果表明,在所有Si含量下,铅铋对屈服强度和最大抗拉强度均没有显著影响,铅铋的影响主要体现在延伸率出现了明显下降;屈服强度随Si含量的变化基本保持不变,最大抗拉强度则呈现小幅度增大趋势;在氩气环境中,延伸率随Si含量的增加而增大.在贫氧铅铋环境中,延伸率的下降幅度与Si含量大体呈正相关.这说明Si含量越多,10Cr铁素体/马氏体钢的液态金属脆化敏感性越大.
Effect of Si Alloying on Liquid Metal Embrittlement Susceptibility of 10Cr Ferritic/martensitic Steel in Liquid Lead-bismuth Eutectic
Ferritic/martensitic(F/M)steels are one of most promising candidate materials for the fuel cladding and other reactor core internals of Gen Ⅳ liquid PbBi cooled fast reactors.Alloying Si into F/M steels is a key technological measure that has been taken by the laboratories worldwide to improve the corrosion resistance of F/M steels exposed to the liquid lead-bismuth eutectic(LBE),there is insufficient information on how Si alloying affects the liquid metal embrittlement susceptibility of the steel.In this work,the effects of alloying four different Si contents on the tensile mechanical behavior and LME susceptibility of the 10Cr F/M steels in oxygen-poor or-saturated LBE and argon(Ar)have been investigated,in collaboration with fractographic examinations.The results showed that the LBE environment had little effect on the yield strength and the ultimate tensile strength at all Si contents,while the total elongation to failure was significantly reduced in presence of LBE.Yield strength is not affected much by Si alloying,while the ultimate tensile strength exhibited a slightly increasing trend.The total elongation to failure was strongly dependent on Si content.In Ar environment,the total elongation to failure increases with the increase of Si content,while a reverse trend was observed in the LBE environment.All results suggest that the LME susceptibility was promoted by Si alloying.

PbBiCorrosionFerritic/Martensitic steelsAustenitic stainless steels

卓洪、钟志淮、温涛、肖军、王浩、龚星

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中国核动力研究设计院反应堆燃料及材料重点实验室,四川 成都 610213

深圳大学物理与光电工程学院核科学与核技术系先进核能团队,广东 深圳 518060

深圳大学物理与光电工程学院中国核能与安全高等研究院,广东 深圳 518060

铅铋 腐蚀 铁素体/马氏体钢 奥氏体不锈钢

国家自然科学基金面上基金项目

52271063

2024

核科学与工程
中国核学会

核科学与工程

CSTPCD北大核心
影响因子:0.586
ISSN:0258-0918
年,卷(期):2024.44(2)
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