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火山灰硅酸盐水泥粒径对水化反应的影响

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通过不同细度的筛网和调整磨粉时间获得不同细度的火山灰硅酸盐水泥,试验结合X射线衍射(XRD)、扫描电子显微镜(SEM)技术从微观的角度研究了火山灰硅酸盐水泥的细度对火山灰硅酸盐水泥宏观性能、钙矾石晶体与C-H-S凝胶的影响.结果表明,随着火山灰硅酸盐水泥的细度从224.45 m2·kg-1 增加至576.88 m2·kg-1,抗压强度与抗折强度提高,火山灰硅酸盐的水泥凝结时间下降,标准稠度用水量提高.结合XRD、SEM进行微观分析,利用SEM技术观察出水化产物为钙矾石晶体与C-H-S凝胶,通过XRD技术物相分析发现随着细度的增加钙矾石晶体峰值与Ca(OH)2 峰值逐步提升,得出不同细度的火山灰硅酸盐水泥水化产物随着水泥细度的增大而增多.
Influence of particle size of volcanic ash silicate cement on its hydration reaction
Different fineness of volcanic ash silicate cement were obtained by different fineness of sieves and adjustment of grinding time.The effect of fineness of volcanic ash silicate cement on the macroscopic properties of volcanic ash silicate cement was investigated from a microscopic point of view by combining X-ray diffraction(XRD)and scanning electron microscopy(SEM)techniques.The results showed that as the fineness of volcanic ash silicate cement increases from 224.45 m2·kg-1 to 576.88 m2·kg-1,the compressive and flexural strengths increase,the setting time of the cement of volcanic ash silicate decreases and the water consumption of the standard consistency increases.The hydration products were observed to be calcium alumite crystals and C-H-S gels by XRD and SEM,and the peak values of calcium alumite crystals and Ca(OH)2 were found to increase with increasing fineness by XRD.

pozzolanic cementfinenessXRDSEMsetting timerequirement of normal consistency

宗翔、刘睿、王亮

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安徽理工大学土木建筑学院,安徽淮南 232001

火山灰硅酸盐水泥 细度 X射线衍射 扫描电子显微镜 凝结时间 标准稠度用水量

国家自然科学基金

52108187

2024

哈尔滨商业大学学报(自然科学版)
哈尔滨商业大学

哈尔滨商业大学学报(自然科学版)

影响因子:0.405
ISSN:1672-0946
年,卷(期):2024.40(1)
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