首页|高选择性位阻胺脱硫剂试用研究

高选择性位阻胺脱硫剂试用研究

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某石化公司溶剂再生装置脱硫溶剂采用MDEA溶剂,其选择性稍差,吸收H2S的同时吸收大量的CO2,溶剂再生酸性气中CO2浓度高达70%,造成下游硫磺回收装置出现诸多生产问题.对此,该公司参考同类装置,最终决定采用含位阻胺溶剂来提高溶剂再生装置胺液选择性,降低脱硫过程胺液对CO2的吸收率,从而降低再生酸性气量,提高酸性气中H2S占比,确保硫磺装置稳定运行.通过测试,加入位阻胺成分后溶剂较之未加入前CO2滑脱率提升超过20%,提升了溶剂再生装置系统内溶剂质量.
Trial study of high selective steric hindrance amine desulfurizer
MDEA solvent with poor selectivity was used as the desulfurizing solvent in the solvent recycling plant of a petrochemical company which absorbed H2S and a large amount of CO2,led to the CO2 concentration in the solvent recycling acid gas up to 70%that resulted in some production problems to downstream sulfur recovery plant.Therefore,referred to the similar plants,the company finally decided to use a steric amine solvent to improve the selectivity of the amine solution of the solvent regeneration plant,reduced the absorption rate of CO2 of the amine solution in the desulfurization process,thereby reducing the acidic gas volume of the regeneration,increasing the proportion of H2S in the acidic gas,and ensuring the stable operation of the sulfur plant.Through the test,the CO2 slippage rate of the solvent increased by more than 20%after the addition of steric amine,which improved the solvent quality in the solvent regenerator system.

sterically hindered aminesolvent selectivityslippage ratesulfur recovery

李晶、张宁峰、李振刚、姜磊

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中国石油宁夏石化公司,宁夏银川 750026

位阻胺 溶剂选择性 滑脱率 硫磺回收

2024

炼油与化工
黑龙江省石油学会,大庆石化公司

炼油与化工

影响因子:0.185
ISSN:1671-4962
年,卷(期):2024.35(2)
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