炼油与化工2024,Vol.35Issue(4) :1-11.

铁基加氢催化剂活性相的构建及加氢脱硫性能研究

Study on construction of active phase and hydrodesulfurization performance of Fe-based hydrogenation catalyst

申宝剑 李国省 任申勇
炼油与化工2024,Vol.35Issue(4) :1-11.

铁基加氢催化剂活性相的构建及加氢脱硫性能研究

Study on construction of active phase and hydrodesulfurization performance of Fe-based hydrogenation catalyst

申宝剑 1李国省 2任申勇1
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作者信息

  • 1. 中国石油大学(北京)化学工程与环境学院CNPC催化重点实验室 重质油全国重点实验室,北京 102249
  • 2. 中国石油大学(北京)化学工程与环境学院CNPC催化重点实验室 重质油全国重点实验室,北京 102249;菏泽学院化学化工学院,山东菏泽 274015
  • 折叠

摘要

综述了铁(Fe)基加氢脱硫(HDS)催化剂的研究进展,为开发高效且经济的金属加氢催化剂提供了重要方向.文中基于该课题组多年来在Fe基HDS催化剂领域的研究,系统总结了 Fe基HDS催化剂的研究历程,重点阐述了 Fe基催化剂的电子结构调控机制及其对HDS性能的影响.此外,分析了 Fe基催化剂在二苯并噻吩(DBT)和4,6-二甲基苯并噻吩(4,6-DMDBT)上的HDS反应机理,为设计和开发低成本HDS催化剂提供了思路.

Abstract

The article provides a comprehensive overview of the research progress in iron(Fe)-based hydrodesulfurization(HDS)catalysts,offering crucial insights into the development of efficient and economical metal-based hydrogenation catalysts.Drawing upon years of research conducted by our research group in the field of Fe-based HDS catalysts,this paper systematically summarizes the evolution of Fe-based HDS catalysts,with a particular emphasis on elucidating the electronic structure modulation mechanisms of Fe-based catalysts and their subsequent impact on HDS performance.Furthermore,it delves into the analysis of the HDS reaction mechanisms of Fe-based catalysts in the presence of dibenzothiophene(DBT)and 4,6-dimethyldibenzothiophene(4,6-DMDBT),offering valuable insights into the catalytic processes.This comprehensive review serves as a roadmap for the design and development of low-cost HDS catalysts.

关键词

Fe基催化剂/加氢脱硫/电子结构调控/电子助剂

Key words

Review/Fe-based catalyst/hydrodesulfurization/electronic structure regulation/electronic promoter

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出版年

2024
炼油与化工
黑龙江省石油学会,大庆石化公司

炼油与化工

影响因子:0.185
ISSN:1671-4962
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