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铁基加氢催化剂活性相的构建及加氢脱硫性能研究

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综述了铁(Fe)基加氢脱硫(HDS)催化剂的研究进展,为开发高效且经济的金属加氢催化剂提供了重要方向.文中基于该课题组多年来在Fe基HDS催化剂领域的研究,系统总结了 Fe基HDS催化剂的研究历程,重点阐述了 Fe基催化剂的电子结构调控机制及其对HDS性能的影响.此外,分析了 Fe基催化剂在二苯并噻吩(DBT)和4,6-二甲基苯并噻吩(4,6-DMDBT)上的HDS反应机理,为设计和开发低成本HDS催化剂提供了思路.
Study on construction of active phase and hydrodesulfurization performance of Fe-based hydrogenation catalyst
The article provides a comprehensive overview of the research progress in iron(Fe)-based hydrodesulfurization(HDS)catalysts,offering crucial insights into the development of efficient and economical metal-based hydrogenation catalysts.Drawing upon years of research conducted by our research group in the field of Fe-based HDS catalysts,this paper systematically summarizes the evolution of Fe-based HDS catalysts,with a particular emphasis on elucidating the electronic structure modulation mechanisms of Fe-based catalysts and their subsequent impact on HDS performance.Furthermore,it delves into the analysis of the HDS reaction mechanisms of Fe-based catalysts in the presence of dibenzothiophene(DBT)and 4,6-dimethyldibenzothiophene(4,6-DMDBT),offering valuable insights into the catalytic processes.This comprehensive review serves as a roadmap for the design and development of low-cost HDS catalysts.

ReviewFe-based catalysthydrodesulfurizationelectronic structure regulationelectronic promoter

申宝剑、李国省、任申勇

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中国石油大学(北京)化学工程与环境学院CNPC催化重点实验室 重质油全国重点实验室,北京 102249

菏泽学院化学化工学院,山东菏泽 274015

Fe基催化剂 加氢脱硫 电子结构调控 电子助剂

2024

炼油与化工
黑龙江省石油学会,大庆石化公司

炼油与化工

影响因子:0.185
ISSN:1671-4962
年,卷(期):2024.35(4)