In order to explore the characteristics of Bola surfactants,the synthesis and micellization behavior of Bola surfactants were proposed.L-tyrosine and 1,12-diaminododecane were used as raw materials for the synthesis of Bola surfactant,and the Bola surfactant product with light yellow powder was obtained.The critical micelle concentration of Bola surfactants was determined by conductivity method and isothermal titration calorimetry method respectively,and the thermodynamic behaviors of micellization of Bola surfactants with different concentrations were statistically analyzed.It was determined that the increase of entropy(that is,the disorder of the system)was the main driving force of the micellization process of Bola surfactants.
关键词
Bola型表面活性剂/L-酪氨酸/1,12-二氨基十二烷/临界胶束浓度/胶束化热力学行为
Key words
bola surfactant/L-tyrosine/1,12-diaminododecane/critical micelle concentration/thermodynamic behavior of micellization