首页|基于Fe3O4@C纳米粒子的光子晶体水凝胶薄膜的柔性应变传感器

基于Fe3O4@C纳米粒子的光子晶体水凝胶薄膜的柔性应变传感器

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颜色变化作为视觉信号反馈最直观的方式,常被生物体用来传递信号和抵抗天敌.受变色龙皮肤结构色变化的启发,研制了一种可用于柔性应变检测的光子晶体水凝胶薄膜.采用Fe3O4@C纳米粒子作为光子晶体单元,利用其在磁场作用下可在水凝胶中自组装成一维链状结构,通过紫外光固化技术,成功制备具有明亮结构色的柔性光子晶体水凝胶薄膜.由于薄膜的结构色会随着光子晶体的带隙变化而发生改变,该薄膜在机械拉伸作用下会产生协同的颜色变化.所制备的柔性薄膜结构颜色明亮,应变响应宽达120%,并实现了从红色(λ=730 nm)到紫色(λ=400 nm)的颜色动态变化.此外,制备的该薄膜具有灵敏度高、响应时间短、稳定性好等特点.柔性应变检测的优异性能归功于水凝胶膜的柔性大变形和良好的光学特性以及光子晶体高度可调谐光栅结构.这项工作为视觉响应应变传感器的发展提供了一种通用的方法,并在机械传感器、可拉伸光学和诊断方面提供了更广阔的应用前景.
Flexible strain sensor based on photonic crystal hydrogel film doped with Fe3O4@C nanoparticles
As the most intuitive way of visual signal feedback,color change is often applied by living organisms to transmit signals and resist natural enemies due to its convenient and direct characteristics.Inspired by the structure color charge of discoloration of chameleons skin,a photonic hydrogel film that can be used for flexible strain detection was developed.Fe3O4@C nanoparticles were used as photonic crystal units,which could self-assemble into one-dimensional chain-like structure in the hydrogel under magnetic field.The structural color of the film will change with the photonic crystal band gap,the film will produce a synergistic color change under mechanical stretching.The resulting flexible film demonstrates bright structural colors,which exhibits a wide strain response up to 120%and achieves a color dynamic change from red(λ=730 nm)to purple(λ=400 nm).In addition,the prepared film exhibits high sensitivity,short response time and good stabilization.The superior performance of flexible strain detection is attributed to the flexible large deformation and good optical properties of the hydrogel film and highly tunable grating structure of the photonic crystal.This work offers a generic approach for the development of visually responsive strain sensors,and provides a wider application prospect in mechanical sensors,stretchable optics,and diagnostics.

Fe3O4@C nanoparticleshydrogel filmphotonic crystalstructural colorflexible strain sensor

庄严、龚开、姜子实、王强、李鹏

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黑龙江大学物理科学与技术学院,哈尔滨 150080

Fe3O4@C纳米粒子 水凝胶薄膜 光子晶体 结构色 柔性应变传感器

国家自然科学基金项目黑龙江省自然科学基金项目

11704105YQ2021008

2024

黑龙江大学工程学报
黑龙江大学

黑龙江大学工程学报

影响因子:0.358
ISSN:2095-008X
年,卷(期):2024.15(3)