首页|秸秆衍生多孔碳的制备及其在电化学吸附水中铜离子方面的应用

秸秆衍生多孔碳的制备及其在电化学吸附水中铜离子方面的应用

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由于重金属离子对水环境的污染及人类健康的危害较大,重金属离子的净化技术正受到前所未有的重视.电容去离子作为一种新兴的水处理方法,具有快速、简便的优点,能有效从水溶液中去除重金属离子.以玉米秸秆为碳源,KOH为活化剂,通过一步高温碳化法制得了玉米秸秆衍生多孔碳(Corn Stover Porous Carbon,CSPC)材料.制备的CSPC材料表面粗糙,具有丰富的孔道结构及较大的比表面积,使其具有良好的电容去离子性能.在最佳的操作条件下,该电极材料对铜离子电极吸附量可至6.17 mg·g-1,具有良好的循环稳定性.
Preparation of porous carbon derived from stover for electrochemical adsorption of copper ions in water
The purification technology of heavy metal ions is receiving unprecedented attention due to the pollution of the water environment and the danger to human health.Capacitive deionization,as an emerging water treatment method,is a fast and simple method to effectively remove heavy metal ions from aqueous solutions.In this paper,corn stover porous carbon(CSPC)materials were prepared by one-step high temperature carbonization method using corn stover as carbon source and KOH as activator.The surface of the prepared CSPC material exhibited rich pore structure and large specific surface area.These properties resulted in the prepared CSPC materials with good capacitive deionization performance.By optimization of the reaction conditions,the electrode material could reach 6.17 mg·g-1 for copper ion electrode adsorption under the optimal operating conditions with very good cyclic stability.

corn stoverbiomass charcoalcopper ioncapacitive deionization

李清阳、刘金桥、汪立学、万家峰

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黑龙江大学化学化工与材料学院,哈尔滨 150080

玉米秸秆 生物炭 铜离子 电容去离子

国家自然科学基金项目黑龙江省自然科学基金项目

52070074LH2022B018

2024

黑龙江大学工程学报
黑龙江大学

黑龙江大学工程学报

影响因子:0.358
ISSN:2095-008X
年,卷(期):2024.15(3)