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造纸废水污泥脱水试验研究

Experimental Study on Dewatering of Papermaking Wastewater Sludge

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本研究旨在探究造纸废水污泥调理改性后污泥脱水的效果,采用造纸厂污泥为样本,对其基本特性进行分析,并运用Fenton氧化联合氧化钙调理方法优化污泥脱水性能.最佳调理改性条件为初始pH 3.0,Fe2+和H2O2的投加量各为30mg/gDS.调理改性后污泥的比阻(SRF)显著降低,泥饼含水率减少,且胞外聚合物(EPS)中蛋白质和多糖浓度变化明显,有机物组成发生显著改变.红外光谱分析进一步证实污泥有机物结构的变化,Fenton联合氧化钙调理能有效改善造纸污泥的脱水性能.
The aim of this study is to explore the effect of sludge dewatering after conditioning and modi-fication of papermaking wastewater sludge.Using paper mill sludge samples,the basic characteristics were analyzed,and the Fenton oxidation combined with calcium oxide conditioning method was used to optimize the sludge dewatering performance.The optimal conditioning conditions are an initial pH of 3.0,and the dosage of Fe2+and H2O2 is 30 mg/gDS each.After conditioning and modification,the specific resistance(SRF)of the sludge was significantly reduced,the moisture content of the sludge cake was reduced,and the concentration of proteins and polysaccharides in the extracellular polymer(EPS)changed significantly,resulting in a significant change in the composition of organic matter.Infrared spectroscopy analysis further confirmed the changes in the organic structure of sludge,and Fenton com-bined with calcium oxide conditioning can effectively improve the dewatering performance of papermak-ing sludge.

paper wastewater sludgesludgedewateringFenton oxidationcalcium oxide

熊霞、程涛、何光亚

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安徽省通源环境节能股份有限公司,安徽合肥 230031

安徽省市政污泥处置与资源化利用工程研究中心,安徽合肥 230031

造纸废水污泥 污泥脱水 Fenton氧化 氧化钙

安徽省重点研究与开发计划项目

2023t07020011

2024

黑龙江造纸
黑龙江省造纸工业研究所 黑龙江省造纸学会

黑龙江造纸

影响因子:0.176
ISSN:1673-0283
年,卷(期):2024.52(2)