首页|工业固废碳化固化淤泥的力学性能及机理研究

工业固废碳化固化淤泥的力学性能及机理研究

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为改善淤泥的力学特性,提高其抗变形能力,采用电石渣、粉煤灰与矿渣作为环保固化剂,联合CO2碳化固化淤泥.通过加速碳化试验、无侧限抗压强度试验、X射线衍射(XRD)和电镜扫描(SEM),对比分析不同固化剂掺量、碳化时间、碳化深度对试样力学性能和微观结构的影响.结果表明:碳化6 h试样抗压强度得到明显提升,提升幅度为16%~25%;试样强度随着碳化时间先增加后减小,最佳碳化时间为6 h左右;碳化6 h后的pH值从11~14降低到10~12;固化淤泥碳化深度与碳化时间的平方根近似为线性关系;碳化后试样破坏,应变基本不变,但峰值应力明显增大,碳化试样变形模量高于未碳化试样;工业固废碳化固化淤泥试样所生成的水化产物为CaCO3晶体,以针状的文石和方形的方解石形式存在,共同构建土体内部骨架,形成非常密实的交叉体系.
Mechanical properties and mechanism of industrial solid waste carbonized solidified sludge
To improve the mechanical properties of sludge and increase its resistance to deformation,a new type of environment-friendly solidified agent with carbide slag,fly ash and slag,combined with CO2 to carbonize and solidify sludge.Through the unconfined compression test,accelerated carbonation test,X-ray diffraction(XRD)and scanning electron microscopy(SEM),the effects of different solidification agent content,carbonation time,carbonation depth on the mechanical properties and microstructure of the samples were compared and ana-lyzed.The results show that:the compressive strength of carbonized 6 h samples was significantly increased by 16%~25%;the strength of the sample increases first and then decreases with the carbonation time,and the op-timum carbonation time is about 6 h;after carbonizing for 6 h,the pH value decreases from 11~14 to 10~12;the square root of carbonization depth and carbonization time of solidified silt can be approximately regarded as linear relationship;after carbonization,the sample is damaged,the strain is basically unchanged,but the peak stress increases obviously,and the deformation modulus of carbonized sample is higher than that of uncarbon-ized sample;the hydrated product produced by carbonizing solidified sludge samples of industrial solid waste is CaCO3 crystal,which exists in the form of acicular aragonite and square calcite,and jointly constructs the inter-nal skeleton of soil,forming a very dense cross system.

industrial solid wastecarbonation and solidificationsolidified sludgemechanical propertiesmi-croscopic mechanisms

方子航、王强、张俊毅

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安徽理工大学土木建筑学院,安徽 淮南 232001

工业固废 碳化固化 固化淤泥 力学特性 微观机制

安徽理工大学环境友好材料与职业健康研究院研发专项基金大学生创新创业训练计划项目

ALW2020YF13S202210361052

2024

河南城建学院学报
河南城建学院

河南城建学院学报

影响因子:0.457
ISSN:1674-7046
年,卷(期):2024.33(1)
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