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碳酸盐对三元复合水泥砂浆抗压强度和孔隙结构的影响

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为研究不同碳酸盐(石灰石、白云石、菱镁矿)和非碳酸盐(石英石)对三元复合水泥砂浆抗压强度和孔隙结构的影响,在水胶比为 0.45 的条件下,制备了三元复合水泥砂浆和净浆试样,其中水泥的掺量为55%,偏高岭土为30%,可变组分为15%.结果表明,当养护龄期为28d时,含有碳酸盐的三元复合水泥砂浆的孔隙结构得到了细化,其抗压强度显著提升.然而,当养护龄期为90d时,含有非碳酸盐的三元复合水泥砂浆中生成了大量的水化硅铝酸钙,其抗压强度因此超过了含有碳酸盐的三元复合水泥砂浆.与纯水泥砂浆相比,单位质量的三元复合水泥砂浆的二氧化碳排放量降低约 30%,对推动绿色建筑的发展具有重要意义.
Effects of carbonate on compressive strength and pore structure of ternary composite cement mortar
To study the effects of different carbonates(limestone,dolomite,magnesite)and non-carbonates(quartz)on the compressive strength and pore structure of ternary composite cement mortars,ternary composite cement mortar and paste samples were prepared under a water-to-binder ratio of 0.45,with 55%cement,30%metakaolin,and 15%variable components.The results indicated that after 28 days of curing,the pore structure of the ternary composite cement mortar containing carbonates was refined,significantly enhancing its compres-sive strength.However,after 90 days of curing,a large amount of calcium silicate hydrate formed in the ternary composite cement mortar containing non-carbonates,causing its compressive strength to exceed that of the com-posite cement mortar with carbonate components.Compared to pure cement mortar,the carbon dioxide emis-sions per unit mass of the ternary composite cement mortar were reduced by about 30%,which is of significant importance for promoting the development of green buildings.

cement mortarhydration reactionmicrostructurecarbon emissions

李高阳、陈海明、陈卓恒、陈杰

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安徽理工大学 土木建筑学院,安徽 淮南 232001

安徽理工大学 矿山地下工程教育部工程研究中心,安徽 淮南 232001

水泥砂浆 水化反应 微观结构 碳排放量

2024

河南城建学院学报
河南城建学院

河南城建学院学报

影响因子:0.457
ISSN:1674-7046
年,卷(期):2024.33(6)