首页|超亲水/超疏水表面对铜基换热性能的影响

超亲水/超疏水表面对铜基换热性能的影响

扫码查看
本文主要研究了铜制件表面超亲水/超疏水处理后,对铜基表面耐腐蚀性和换热效率的影响.实验探究得到超亲水工艺条件:在1 mol/L NaOH和0.5 mol/L NH4Cl混合溶液中与2.0 mA/cm2的电流密度下电沉积30 min,得到最佳亲水角5°的氢氧化铜纳米线层超亲水膜.超疏水最佳工艺条件:在0.1 mol/L十四酸乙醇溶液中与电压30V时电沉积时间60 min,得到最佳疏水角158°的十四醋酸铜超疏水膜.通过塔菲尔曲线分析了超亲水/超疏水铜基表面的耐腐蚀性能,结果表明超亲水/超疏水铜表面具有更加优异的耐腐蚀性能,分别提升了4个和2个数量级.通过此方法处理铜基表面,发现其冷凝水量明显增加,换热效率提升了38.3%,强化了铜基表面的换热,增强了换热效率,可用于铜基换热器的表面处理.
Effect of Superhydrophilic and Superhydrophobic Surfaces on Copper Based Heat Transfer Performance
The heat transfer and corrosion resistance of copper can be improved by super hydrophilic and superhydrophobic surfaces based on heat exchangers due to their special wetting properties.This article mainly studies the effect of superhydrophilic and superhydrophobic treatment on the corrosion resistance and heat transfer efficiency of copper based surfaces.The experimental investigation presents the superhydrophilic process conditions:electrodepositing for 30 minutes in a mixed solution of 1 mol/L NaOH and 0.5 mol/L NH4Cl at a current density of 2.0 mA/cm2,obtaining a copper hydroxide nanowire layer superhydrophilic film with an optimal hydrophilicity angle of 5°.The optimal process conditions for superhydrophobicity:electrodeposition of copper tetradecanoate superhydrophobic film with an optimal hydrophobic angle of 158°was obtained in 0.1 mol/L tetradecanoate ethanol solution at a voltage of 30 V for 60 minutes.The corrosion resistance of superhydrophilic superhydrophobic copper based surfaces is analyzed through Tafel curves,and the results show that superhydrophilic superhydrophobic copper surfaces have better corrosion resistance,with an increase of 3 and 1 order of magnitude,respectively.By using this method to treat copper based surfaces,it is found that the condensation water amount significantly increases,and the heat transfer efficiency increases by 38.3%.This strengthens the heat transfer on the copper based surface and enhances the heat transfer efficiency,making it suitable for surface treatment of copper based heat exchangers.

super hydrophilicsuper hydrophobicityheat exchangercorrosion resistanceheat exchange performance

刘泽澎、曾丽萍、易翔、王平、杨新杰

展开 >

湖南工程学院 绿色低碳建筑节能与材料技术湖南省工程研究中心,湘潭 411104

湖南工程学院 材料化工学院,湘潭 411104

超亲水 超疏水 换热器 耐腐蚀性能 换热性能

国家重点研发计划湖南省教育厅优秀青年项目

2018YFE011120020B133

2024

湖南工程学院学报(自然科学版)
湖南工程学院

湖南工程学院学报(自然科学版)

影响因子:0.265
ISSN:1671-119X
年,卷(期):2024.34(1)
  • 19